用于CO2分离的有机无机杂化膜的制备和性能研究.docVIP

　 PAGE 29 - PAGE 2 - PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT 1 用于CO2分离的有机无机杂化膜的制备和性能研究 摘 要：聚氨酯对C02气体分离具有一定的选择性，而氧化石墨烯（GO）在气体分离过程中也表现出良好的选择性和渗透性，将GO掺杂到PU中制成GO/PU杂化膜在C02气体膜分离中具有潜在的应用价值。本课首先制备了GO，并对它进行了表征。结果表明：成功制备了含有丰富含氧基团的且分散性比较好的稳定氧化石墨烯。通过制备不同氧化程度、不同填充量的GO/PU杂化膜，对其性能进行研究。结果表明：GO/聚氨酯膜在苯溶剂中对苯分子的溶胀吸附能力明显高于其对在环己烷溶液中的吸附，这表明GO/PU膜对苯有优先选择吸附，，其中，氧化程度为GO-4、填充量为5wt%时，对于苯和环己烷的吸附量最大；在氧化程度为GO-4，填充量为1wt%时，GO/PU杂化膜对CO2气体膜分离的综合效果最好，其对CO2/N2的分离因子高达46.2，CO2渗透速率为1.67*10-9(cm3/cm2.s.Pa)，这表明GO/PU杂化膜对于CO2气体分离性能好，在CO2气体分离领域具有极高的应用价值。 关键词：CO2膜分离；氧化石墨烯；聚氨酯；GO/PU杂化膜 Preparation and property of organic/inorganic hybrid membrane for CO2 separation Abstract: Polyurethane is an ideal polymeric material which has some separation selectivity of the C02 gas , graphene oxide in the process of gas separation also reflects the good permeability and selectivity. The GO doped into PU makes the C02 gas membrane separation of GO / PU hybrid membrane has a potential applications .This paper prepared graphene oxide ，and study its properties. The results showed that successfully prepared a good stable graphene oxide rich in oxygen-containing groups and dispersed.Prepared different degree of oxidation and different loadings of GO / PU hybrid film,and study its propertiesThe results showed that Graphene oxide / polyurethane hybrid membrane sorption of benzene and cyclohexane, are preferred with the selective adsorption of benzene., and the degree of oxidation of GO-4, when the filling amount of 5wt%, the absorption maximum of benzene and cyclohexane; the degree of oxidation of GO-4, when the filling amount of 1wt%, GO / PU hybrid membrane CO2 the combined effect of gas separation membrane best, the separation factor of CO2/N2 up to 46.2, CO2 permeation rate of 1.67 * 10-9 (cm3/cm2.s.Pa). This indicates GO / PU hybrid membranes for CO2 gas separation performance is very good, with a high CO2 gas separation applications in the field. Keywords: C02 membrane separation ; Graphene oxide; Po