环境友好石墨烯-高分子杂化膜制备研究.docVIP

PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT １ PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT ０ 环境友好石墨烯——高分子杂化膜制备研究 摘 要：无机物的分散效果对杂化膜的制备很重要。本文在制备了氧化石墨烯（GO）后制备了氧化石墨烯与聚氨酯的杂化膜（GO/PU）及氧化石墨烯/聚亚酰胺(GO/PI)杂化膜，并对其性能进行研究。氧化石墨烯的氧化程度越高，就能提高亲水性和分散效果；同时，氧化石墨烯的填充量越高，就越有可能发生团聚现象，从而降低其分散性；另外，氧化程度过高也可能会过度破坏内部结构而影响其分离率。GO/PU杂化膜和GO/PI杂化膜都对苯的溶胀吸附更大。并且二者都是在GO-4的填充量为1wt%时对CO2/N2混合气的选择性最好，而氧化石墨烯/聚氨酯的混合气选择性又比氧化石墨烯/聚亚酰胺的选择性更好，其分离比分别是46.21和12.69。 关键词：氧化石墨烯；聚氨酯；聚亚酰胺；杂化膜 Environment friendly graphene research ——polymer hybrid membrane preparation Abstract: Dispersion of inorganic hybrid membranes prepared for very important.This paper prepared graphene oxide, and prepared graphene oxide / polyurethane and graphene oxide / polyimide hybrid membrane, and study its properties. The higher the degree of oxidation of the graphene oxide, the better of the hydrophilicity, the better of the dispersion; Meanwhile, the higher the fill level of the graphene oxide, the more likely the occurrence of agglomeration, thereby reducing its dispersion; In addition, the high degree of oxidation may also affect the internal structure of overkill separation rate .Graphene oxide / polyurethane and graphene oxide / polyimide hybrid membrane sorption of benzene and cyclohexane, are preferred with the selective adsorption of benzene. And both are the best in the CO2/N2 selectivity of the gas mixture when the filling amount of GO-4 is 1 wt% , the graphene oxide / polyurethane ’s selectivity is better than the polyimide’s. Keywords: grephene oxide;polyurethane;polyimide;hybrid membrane 正文目录 TOC \o 1-2 \h \u HYPERLINK \l _Toc27130 1引言 PAGEREF _Toc27130 1 HYPERLINK \l _Toc1515 1.1研究背景和意义 PAGEREF _Toc1515 1 HYPERLINK \l _Toc15258 1.2研究现状及分析 PAGEREF _Toc15258 1 HYPERLINK \l _Toc187 1.3实验思路总结 PAGEREF _Toc187 2 HYPERLINK \l _Toc14016 2. 氧化石墨烯的制备 PAGEREF _Toc14016 3 HYPERLINK \l _Toc7334 2.1引言 PAGEREF _Toc7334 3 HYPERLINK \l _Toc19073 2.2实验试剂与表征仪器 PAGEREF _Toc19073 3 HYPERLINK \l _Toc317