马来酸酐接枝聚乙烯改性氢氧化铝聚乙烯体系性能研究.PDFVIP

28 2 Vol. 28, No . 2 2007 6 Journal of Hebei University of Science and T echnolo y June 2007 : 1008- 1542( 2007) 02-0110- 04 / 1 2 付朝霞 , 段玉丰 ( 1. 河北科技大学科研处, 河北石家庄 050018 ; 2. 河北科技大学材料科学与工程学院, 河北石家 庄 050054) : 将马来酸酐与聚乙烯进行反应, 红外 谱显示马来酸酐接枝到聚乙烯分子链上, 然后用马 来酸酐接枝聚乙烯处理氢氧化铝表面, 将马来酸酐接枝聚乙烯处理的氢氧化铝与聚乙烯熔融混合 后, 考察流变力学阻燃性能及微观形态变化结果显示, 采用适量马来酸酐接枝聚乙烯对氢氧化 铝进行表面处理, 可以改善体系混炼过程的熔体流动性, 增强力学性能, 但氧指数无显著变化; SEM 测试显示氢氧化铝在聚乙烯基相中达到了更好的分散 : 氢氧化铝; 马来酸酐接枝; 聚乙烯; 流变性能; 力学性能 : T Q225. 13 : A Properties of poly ethylene/ AT H treated w ith PE- - MAH 1 2 FU Zhao-xia , DUAN Yu-fen ( 1. Of fice of Science and Research, Hebei University of Science and T echnolo y, Shijiazhuan H ebei 0500 18, China; 2. Colle e of Materials Science and En ineerin , H ebei University of Science and T echnolo y, Shijiazhuan Hebei 050054, China) Abstract: Maleic anhydride reacts w ith poly et hylene ( PE- -MA H) and FT IR spectra proves maleic anhydride is rafted to po- lyethylene. Aluminium trihydrox ide( AT H ) treated wit h the PE- -MA H is melt and blended with polyethylene. The rheolo i- cal property , mechanical propert ies, fire retardance and morpholo y of PE/ AT H composites are investi ated. The data indi- cates that the rheolo ical and the mechanical properties are improved w hile AT H is treated w ith PE- -MA H of the ri ht dos- a e. H ow ever, the LOI is hardly chan ed. It is found that better dispersion is achieved when AT H is treated with PE- -MA H under SEM . Key words: aluminium trihy drox ide; maleic anhydride raft in ; polyethylene; rheolo ical property ; mechanical propert ies ( ATH) , , [ 1~ 4]