猪肉中63种有机磷农药的气相色谱筛选与气质联用确证方法.PDFVIP

27 12 V ol127 N o1 12 2008 12 FEN X I CESH I XU EBAO ( Journal of Ins trum en tal A naly s s) 1298~ 1302 63 苏建峰 ( , 350015) : - - 63 - , , C 18 PSA GC G C- M S ( FPD ) , - ( SIM ) , , ( S /N = 10 ) 01 001~ 01043 mg / kg, 01 16 mg / kg , 70% ~ 121% , 411% ~ 131 9% : - ; ; ; ; ; ; ; : O 65717 1; S4811 8 : A : 1004- 4957 ( 2008) 12- 1298- 05 D eterm nat on of 63 O rganophosphrous P est c des R es dues n Pork by G as Chrom atography and G as Chrom atography- M ass Spectrom etry SU J an-feng ( Fu j an Fa rreach Food Sa fe ty T est ng Co1, L td1, Fuzhou 350015, Ch na) Abstract: A m ethod for determ nat on o f 63 organophosphrous pest c des res dues n pork sam p le w as descr bed by so l d phase ex tract on ( SPE ) /gas chrom atog raphy w th flam e photom etr c detect on ( FPD) and gas chrom atog raphy - m ass spectrom etry( G C - M S) . T he res dues w ere ex tracted from hom ogen zed t ssue w th aceton tr le- w ater ass sted by n-hexane, and separated w th l qu d- l qu d part t on. T he supernatant l qu d w as cleaned up by SPE ( C18 and PSA co lum ns). The separat on and determ nat on o f ana ly tes w ere perform ed by u s ng GC and GC - M S w th se lected on m on tor ng ( SIM ) m ode and ex terna l standard m ethod. The cond t ons o f pretreatm ent and determ nat on w ere nvest gated. T he m ethod w as conven ent