锂硫电池正极结构设计、材料制备及电化学性能研究-无机化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ABSTRACTWi ABSTRACT Wi吐1 the development of society and economy，energy supply has become one of the most universal society issues．The pursuit of advanced energy storage devices with higher energy densities are critical for powering Our future society．Lithium／sulfur(Li／S)batteries are well known aus the most promising energy storage system for decades due to its high theoretical capacity(1 675 rnAWg)and energy density(2600 Wr依g)，which is four times the energy density of conventional lithium-ion batteries．In addition,sulfur is abundant，low cost and environmental friendly． Despite all these advantages，Lithium／sulfur batteries still have not been commercialized for large scale utilization．The poor cycling life，low efficiency and low active material utilization are considered aS the main hindrances，which derive from the following reasons． Firstly，sulfur has a low conductivity(5 lO。30 S cm-1 at 25。C)，which makes it almost electrically and ionically insulated，and leads to poor electrochemical accessibility and low utilization of sulfur in the electrode．Secondly，sulfur is dissolvable in the electrolyte upon the electrochemical reaction．The SO called‘‘shuttle effect’ofsoluble polysulfide originating from its charging-discharging process brings about low coulombic efficiency．Finally，sulfur cathode undergoes extreme volume expansion during cycling．In order to solve the above problems，we put forward three methods to improve lithium sulfur batteries． 1．We have been synthesized a novel lotus root-like carbon fiber with hierarchical pore as sulfur immobilizer for Lithium sulfur cathode materials．Alginate fibers，prepared by nature algae，are excellent materials using for cottonocracy and medical filed extensively．The lotus root-like carbon fibers with hierarchical pores from several nanometers to hundreds nanometers were obtained after simple treatment of alginate fibers and followed by KOH activation．The porous carbon fibers Can load vast sulfur and accommodate vol