普通电场及脉冲电场下的静电纺丝实验研究-动力工程及工程热物理专业论文.pdf.docxVIP

北京化工大学硕士学位论文因为聚合物熔体对温度比较敏感，而且聚合物熔体的粘度不便 北京化工大学硕士学位论文 因为聚合物熔体对温度比较敏感，而且聚合物熔体的粘度不便 于精确调节，所以我们对PVP进行了脉冲电场溶液静电纺丝实验。 首先探索了频率和占空比相对于流量和电压对所得纤维直径的影响 程度，发现占空比的影响程度最大，频率的影响不显著；脉冲电场 纤维的平均直径更细，直径分布更宽。后续需要对不同浓度的PVP 进行研究以明确频率和占空比与聚合物浓度对纤维直径的影响关系， 为理解频率和占空比与熔融聚合物分子链缠结的协同作用对熔体静 电纺丝纤维直径的影响奠定基础。 关键词：酚醛纤维，脉冲电场，频率，占空比，PLLA，熔体静电纺 丝，正交实验 万方数据 ABSTRACTEXPERIMENTAL ABSTRACT EXPERIMENTAL RESEARCH oN ELECTROSPINNING OF NORMAL ELECTRIC FIELD AND PULSED ELECTRIC FIELD ABSTRACT Phenolic fiber is a high-performance material with excellent fire resistant，corrosion—resistant and adsorption filtration．Currently，the preparation method by solution electrospinning is very complex and time— consuming，and the fiber applications also limited in adsorption and filtration fields．In this study，the orthogonal experiment design was applied to arrange the melt electrospinning experiment to prepare the pure phenolic fiber under the normal electric field．The results show that the temperature has the most important effect on the resultant average fiber diameter，followed by voltage，and finally the distance．The optimal preparation condition is 1 60 oC，8 cm，40 kV．The average fiber diameter WaS 4．44 4-O．769m in this case．The thermal property of phenolic fiber Was improved after crosslinked． Melt electrospinning can avoid the problems caused by the solvent and can also take full advantage of spinning materials，which is an eco— friendly and efficient method since no requires of solvent．However，due to the inherent high viscosity and low conductivity of the polymer melt， the obtained fiber diameter usually difficult to be reduced to nanoscale， which limiting the development of melt electrospinning．Existing improved methods can achieve a certain effect，but they will make it more different to control the spinning conditions or need more complex preparation equipments．Aiming at this problem，we introduced pulsed 万方数据 北京化工大学硕士学位论文electric 北京化工大学硕士学位论文 electric field to prepare PLLA(poly—L—lactic acid)melt electrospinning f