生物油脂新型环氧化过程及机理研究NewEpoxidationProcessof.PDFVIP

2009 年第67 卷 化 学 学 报 Vol. 67, 2009 第13 期, 1412～1416 ACTA CHIMICA SINICA No. 13, 1412～1416 ·研究论文· 生物油脂新型环氧化过程及机理研究 陈 旻 蒋平平* 叶 夏 施赛泉 卢 云 (江南大学化学与材料工程学院 食品科学与技术国家重点实验室 无锡 214122) 摘要 以金属有机化合物甲基三氧化铼(MTO)为催化剂, 双氧水为氧化剂新型化学方法合成环氧大豆油. 详细考察了 催化剂在双氧水、溶剂和助剂等因素下的催化性能. 研究了该催化体系在其他油脂环氧化中的应用, 环氧产物的选择 性在 99% 以上. 采用红外光谱法(IR)对产品进行表征. 通过紫外-可见分光光度法(UV-Vis)对催化剂的研究, 发现催化 剂(MTO)在催化环氧化过程中形成催化中间体, 且催化活性很高. 对催化剂和双氧水相互作用机理及新型环氧化反应 的机理进行了初步研究. 关键词 生物油脂; 双氧水; 甲基三氧化铼; 液相环氧化 New Epoxidation Process of Biological Oils and Fats and Its Mechanism Chen, Min Jiang, Pingping* Ye, Xia Shi, Saiquan Lu, Yun (State Key Laboratory of Food Science and Technology, School of Chemical and Material Engineering, Jiangnan University , Wuxi 214122) Abstract Epoxidized soybean oil was synthesized by the new catalyst methyltrioxorhenium (MTO) with H O . The effects of reaction parameters such as hydrogen peroxide, solvent and additives on the epoxida- 2 2 tion of soybean oil were discussed in detail. The epoxidation of other oils through this kind of catalytic sys- tem was investigated and the selectivity to the epoxidized product could reach above 99%. The product was characterized by IR spectrum. It was found that the catalytic intermediates with a high catalytic activity were formed in the epoxidarion process through studies on the UV-Vis spectrum of the catalytic system. The mechanism of interaction between the cata