蓖麻油基防腐涂层的制备及其防腐性能研究物理化学专业论文.docxVIP

coating．The coating．The corrosion p∞cess of org椰c coatiIlg w觞i11veStig纰ed by the potentiodynalnic pol撕z撕on curves and electroche血cal ilIlpe出田【ce spec旬的scopy正IS)． The experimental resuhs showed that tlle corrosion potential of t：he coatiIlg modified by Si02 is-0．809 V and the i|npedanCew觞is 4490 Q；11le conIosion pote矾al of tlle coat吨modified by siliCaS01is一0．825 V觚d此蛳dance is 7055． Q．W1lile也e co盯0sion potential of me co疵lg mo蛳ed by Si02锄d caStor oil is—O．732 V髓d雠 impedance is 220．5 M壶． The dehy帆ed c嬲tor oil w懿pr印ared uSing castor oil嬲p涵evaLl m曲erial趾d uSi ng N{lHS04嬲dehydrat迦agent．1k DCO，epo科coat啦s趾d selfhealing印oXy coati ngs were pr印ared by addiIlg the dehydI疵d caStor oil缸o tlle epoxy coatiIlg．The c签tor oil iodine value had hproved to 23．The IR spec协】m of me coating illIlS仃暑Lted the c嬲t0 r oil d曲Iymated suCcessmlly．The eleC仃0chemical experiInent2Ll results showed tllat the c on．osion potentiaLl of tlle coating modified by debydrated caStor oilis一0．827 V and the im pedance waS is 7836 Q．砌le也e co仃0sion potential of雠dehy妣d c嬲t0Ⅲl sel铀e aliIlg coating is．O．825 V纽d铂呛i】唧edance w嬲is 2687 Q． Key words：^fZlg玎esf研l口，，砂；(妇fD，．D玎； Eleclrochemicnl i，rIpedI撇e spectrosc9py Di rected by：prof． SUN Limei App I i cant for Master degree：BA0 Wuyunga (physical chenlistDr) (C01legc of Chemistr)r觚d Chemical Engin∞ring，I∞er MongoIia UniV粥毋for thc Nati∞alitics，To嘲i∞ 028200，China) 万方数据 目 目 录 第一章绪论 ．1 1．1引言 一1 1．2镁合金的应用 1 1．2．1镁合金介绍 1 1．2．2镁合金的应用 1 1．3镁合金腐蚀 1 1．3．1镁合金自然氧化膜 2 1．3．2镁合金腐蚀种类 2 1．4镁合金防腐 ．2 1．4．1缓蚀剂 2 1．4．2化学转化膜 3 1．4．3微弧氧化 3 1．4．4磁控溅射 4 1．4．5电镀 4 1．4．6有机涂层 4 1．5蓖麻油的应用 ．5 1．5．1蓖麻油介绍 5 1．5．2蓖麻油的应用 5 1．5．3蓖麻油及其衍生物在涂层中的应用 。5 1．6本研究课题的目的与意义 ．7 第二章实验部分 ．8 2．1实验试剂及仪器 ．8 2．1．1实验试剂 8 2．1．2实验仪器 9 2．2镁合金预处理 10 2．2．1打磨 。10 2．2．2超声清洗 。10 2．2．3碱洗 l 0 2．2．4酸洗 ．10 2．3磷酸盐转化膜的制备 11 2．4环氧有机涂层的制备 11 2．5蓖麻油改性环氧有机涂层的制备 1l 万方数据 2．6 2．6 Si02改性环氧有机涂层的制备 ll 2．6．1 SS-200型Si02改性环氧有机涂层的制备 11 2．6．2硅溶胶改性环氧有机涂层的制备 12 2．7脱水蓖麻油改性环氧有机涂层的制备 12 2．7．1脱水蓖麻油的制备 ．12 2．7．2脱水蓖麻油改性环氧有机涂层的制备 ．12 2．7．3脱水蓖麻油基微胶囊的制备 12 2．7．4