低维普鲁士蓝类合物分子磁体与镍纳米线复合材料的制备与磁性研究凝聚态物理专业论文.docxVIP

高波兰州大学博士学位论文 高波兰州大学博士学位论文 Abstract Abstract Recently，the low dimensional materials have attracted much attention for their distinctive properties and potential application．We synthesized FeCrCr Prussian Blue analogue nanowires and MnFe Prussian Blue analogue nanoparticles in order to investigate their low dimensional properties．We also synthesized Ni nanowires composite to develop microwave absorbing nanomaterials．The primary results are as follow： 1．FeCrCr Prussian Blue analogue nanowires with diameters of about 80 nnl have been synthesized with anodic oxide film template—based method．The structure analysis of the nanowires indicates a face centered structure．The elemental result indicates that the structure of the nanowires possess Cr vacancies．The infrared u spectrum reveals that the oxidation states are FeiI_CN—Cr and FeIII_cN．Cr 2．De and Ac magnetic properties of the FeCrCr Prussian Blue analogue nanowires are discussed．A negative magnetization and a low temperature spin glass behavior were observed．We consider that the negative magnetization is due to the different temperature dependent magnetization of the ferromagnetic Fe—Cr and anti—ferromagnetic Cr-Cr．The spin glass behavior is caused by the Cr vacancies in the structure and the competition of the ferromagnetic Fe·-Cr and anti--ferromagnetic Cr-Cr． 3．MnFe Prussian Blue analogue nanoparticles were synthesized by using polyvinyl pyrrolidone(PVP)as a protective matrix．The structure analysis of the nanoparticles indicates a face centered structure．The elemental result indicates that the structure of the nanoparticles possess Fe vacancies．The infrared spectrum and Mrssbauer spectrum reveal that the oxidation states are FetI_CN．Mnlll and FelII_cN．Mnu． 4．De and Ac magnetic properties of the MnFe Prussian Blue analogue nanoparticles are discussed．The infinite，percolating ferrimagnetic cluster expected for fee lattice is broken into separate yet competing ferri··or anti ferro--magnetic II 高波兰州大学博士学位论文