北京市大气中溴代阻燃剂环境行为的研究环境科学专业论文.docxVIP

ZHBCD的模拟值分别为569 ZHBCD的模拟值分别为569 Pg m一、2860 Pg m。3和526 Pg m一。结 果显示北京市大气qbY,PBDE和ZHBCD的水平在高安屯最高，前后 八家和镇海公园次之，中央民族大学最低。 关键词多溴联苯醚，六溴环十二烷，大气，水平，树皮 AB AB STRACT In Beij ing，a large number of products which added Polybrominated diphenyl ethers(PBDEs)and Hexabromocyclododecane(HBCD)as brominated flame retardant are being used．Because of its semivolatile， highly lipophilic，persistent and bioaccumulation，PBDEs and HBCD have been detected in environment media(air,sediment，soil and water) and biological samples．There are no reseach reports about PBDEs and HBCD in the atmospheric environment of Beij ing at present．Therefore， the level of PBDEs and HBCD in the atmosphere of Beij ing were determined in this reseach，and the preliminary study about the primary temporal and spatial distribution mechanism of PBDEs and HBCD in atmosphere of Beij ing were carried out． Atmospheric concentrations(gas and particle phase)of PBDEs (EPBDE：BDE一28，-47，一99，一100，一153，一154，一183，一206，一209) ranged from 57 to 469 Pg m‘3(average 205 Pg m-3)in four seasons of Beijing，and the concentration of BDE．209 ranged from 42 to 387 Pg m‘3 (average 1 75 Pg m。3)，which WaS the main PBDEs congener and accounted for 82．2％of EPBDE；the total the concentrations of HBCD (ZHBCD：Gt．，p．，．},-HBCD)ranged from 20 to 1 764 Pg m．3(average 390 Pg m。3)，and Q．，13．，7-HBCD accounted for 27．6，1 4．3 and 58．O％of ZHBCD respectively．The research found the total concentrations of 4 PBDEs PBDEs and HBCD were greatly influenced by the concentration of total suspended particles(TSP)in the atmosphere of Beij ing，also temperature was an important factor that affected atmospheric concentrations of lower brominated PBDEs congeners．Emerging from the research， commercial Deca—BDE product was the main source of atmospheric pollution in Beijing with contribution rate as high as 84．9％，while the contribution rate of Penta-BDE and Octa—BDE were 7．6％and 7．4％， respectively．The reseach found that the gas-particle distribution constant (109rp)of BDE-28，BD