电泳沉积多孔羟基磷灰石涂层及其性能的研究物理化学专业论文.docxVIP

AbstractAbstract Abstract Abstract Hydroxyapatite[Calo(P04)6(OH)2，HA】exhibits excellent bio-activity property as bioceramic material．However,the brittleness of HA restricts it as a load—bearing bone replacement materials．Owing to titanium and titanium alloy aS the traditional implant materials with excellent mechanical properties，preparation of HA coating based on titanium haS become a hotspot of research in the field of bioceramic material． Three types of HA composite coating(orgafiic，polymeric and inorganic compound) were deposited on titanium substrate used pore producer such aS glucose，starch，chitosan by electrophoretic deposition and then the porous HA coating was obtained by sintering treatment process．The chemical composition，surface morphology,phase composition， and thermal stability of the porous HA coating were characterized by FT-IR，SEM，XRD and TG respectively．The bonding strength between the coating and substrate WaS tested by a shear strength testing experiment，the bio—activity of the coating WaS determined by immersion in simulated body fluid(SBF)．The corrosive resistances were measured by CHI 660C electrochemical analysis in SBF too． The results show that the porous HA coating was obtained by sintering at 700C， with pore diameter about 2-30岬and bonding strength up to 19．6 MPa．The coating surface WaS covered by carbonate．apatite after immersion in 1．5 times ion concentration of SBF(1．5SBF)for 5 days，indicating that the coating possesses a good bio—activity on its surface．Tafel curve and electrochemical impedance indicate that the corrosive resistance of porous HA coating is superior to pure titanium substrate． 矿一 Keywords：hydroxyapatite，titanium substrate，electrophoretie deposition，porosity, bio—activity III 福建师范大学李鹏硕士学位论文 1 W 中文文摘中文文摘 中文文摘 中文文摘 生物活性陶瓷材料是目前作为生物医用材料的研究热点之一，是一种能与人体 骨组织、软组织形成化学键合的陶瓷材料。HA生物活性陶瓷是一种由HA构成的磷 酸钙基生物陶瓷，其中HA是动物骨和牙中的主要无机成分。众多研究表明，相比 于力学性能优异的钛金属及其合金，HA具有良好的生物活性，即有利于植入体材 料与活体组织形成化学键合的特性，对于硬组织替换材料，这种化学键合主要是HA 在界面处的沉积实现的，界面结合强度随时问增长而