带支链的氮硫杂杯4芳烃衍生物的合成与性能有机化学专业论文.docxVIP

摘要Abstract 摘要 Abstract ，▲，盖 Regarded as‘the third supramolecular receptor’along with CIOWIR ethers and cyclodctrins，calixarenes ar e a class of well defined macrocyclic oligomePs of phenols bridged by methylene groups．Owing to their convenient preparation in large quantities， unique three-dimensional cavities，chemical stability,high conformational variable, versatile complexation and re-cognization abilities towards ions or molecules；they have received considerable attentions in recent years．Due to easy modification on both lower and upper rims，appropriate functionalized calixarene derivatives have been widely used in molecular recognition,analytical chemistry,chemical sensing,analog enzymes， bio-medicine and other fields．Calixarene derivatives containing amide,thiourea and urea units have good recognition abilities towards heavy metal ions，transition metal ions and anions．Therefore，studies on their derivation and recognition properties and catalytic performance are in the ascendant．In this paper,calix[4]arene is used as a building block, and a series of calix[4]aRene derivatives containing nitrogen and sul缸are designed and i ^ synthesized，and their binding properties and catalyst performance are studied． Firstly,we synthesized calix[4]arene derivatives with dliral amino alcohol fragment and branched chain． Metal cation extraction experiments demonstrate that new calix[4]arene derivatives show good extraction property towards both soft metal ions and hard metal ions．Because of the difference of structure，the two compounds show different liquid membrane transport properties．Compound 2 can be used as catalyst for Secondly,novel calix[4]arene bridged derivatives with acidamide and Rrea were synthesized by“1+1”condensation reaction．Their recognition properties and liquid membrane transport properties towards metal ions were investigated． Finally,compound 1 reacted respectively with ethyl thiol and mercaptobenzimida- zole in‘‘1+2’’condensation mode to obtain two novel