单桥连双环戊二烯基铼或钼羰基配合物的合成及其催化傅克烷基化反应研究有机化学专业论文.docxVIP

类铼金属配合物催化剂具有用量少、反应条件温和、后处理简单、环境污染小， 类铼金属配合物催化剂具有用量少、反应条件温和、后处理简单、环境污染小， 接近绿色化学等优点。 (3)研究了钼配合物7-9与邻四氯苯醌共同作用，催化不同苯衍生物与多种 烷基化试剂的Friedel．Cratts烷基化反应。结果表明：金属钼羰基配合物／邻四氯 苯醌对Friedel．Crafts烷基化反应因苯衍生物和烷基化试剂的不同而表现出不同 的活性。钼金属配合物／邻四氯苯醌在催化Friedel．Crafts烷基化反应中，与传统 的催化剂相同，均为Lewis酸，但是该类钼金属配合物催化剂具有用量少、催化 剂可回收使用、反应条件温和、后处理简单、环境污染小，接近绿色化学等优点。 (4)用1H NMR、13C NMR、IR光谱及元素分析等手段对合成的新化合物及 催化反应的产物进行了表征。 关键词：单桥连双环戊二烯基铼羰基配合物钼羰基配合物结构催化、 Friedel．Craits烷基化反应 IV 万方数据 AbstractIncreasing Abstract Increasing attention has been paid to the progress on the study of bis(cyclopentadienyl) metal carbonyl complexes．The single bridged bis(cyclopentadienyl)metal carbonyl complexes is one of the most important bis(cyclopentadienyl)metal carbonyl complexes． For the single bridged bis(cyclopentadienyl)metal carbonyl complexes，the structure of bridging groups、the kinds and numbers of substituent group in the cyclopentadienyl have significant impact on the structures and reactive properties，caused this kind of metal complexes is widely used in organic synthesis reaction．Thus it be seen，intensive study of these complexes is of great significance，which will not only enrich and develop the metal organic chemistry theory,but also help for the new model of the highly active， SO it has potential application prospects．This paper synthesis six single bridged bis(cyclopentadienyl)Mo or Re carbonyl complexes，separation and identification of the structure of single bridged bis(cyclopentadienyl)Re carbonyl complexes， investigate the infuences of Bridging atoms to the structure of the compounds； mainly studied the activity of single bridged bis(cyclopentadienyl)Mo or Re carbonyl complexes catalytic Friedel—Crafts alkylation reaction，optimized the catalyst system and the reaction conditions，investigated the affection factors of reaction activity， optimized the catalyst system and the reaction conditions，respectively discussed the possible mechanism of single bridged bis(cyclopentadienyl)Mo Re carbonyl complexes catalytic Fr