二氧化硅粒子的制备及其在石英纤维表面的自组装化学专业论文.docxVIP

采用烧蚀和溶剂浸溶的方法对石英纤维表面涂层进行了处理。通过单 采用烧蚀和溶剂浸溶的方法对石英纤维表面涂层进行了处理。通过单 丝抗拉强度、TG—DSC、XPS和SEM研究了石英纤维表面涂层的最佳处 理条件。结果表明石英纤维的表面涂层经过400℃烧蚀／甲苯溶剂处理已 经基本被处理完全。 采用正硅酸乙酯、水、氨水为原料，乙醇为溶剂，制备了粒径分布均 匀的二氧化硅粒子。通过扫描电镜(SEM)考察了正硅酸乙酯的浓度、氨水 的浓度、水的浓度、反应时间和搅拌速度对生成二氧化硅粒径大小以及粒 径分布的影响。 通过SEM研究了自然沉降法、超声波震荡法以及溶剂挥发法下二氧 化硅粒子在石英纤维表面自组装的形貌。结果表明先将石英纤维表面涂覆 一层铝溶胶，再采用垂直毛细自组装法，可得到二氧化硅粒子完全包覆且 分布均匀的石英纤维。 北京化T人学硕l：论义研究了高温下自组装后的石英纤维与原纤维的单丝抗拉强度的变化。 北京化T人学硕l：论义 研究了高温下自组装后的石英纤维与原纤维的单丝抗拉强度的变化。 结果表明随着对石英纤维处理温度的提高，自组装后的石英纤维与原纤维 的单丝抗拉强度均下降，经过铝溶胶以及二氧化硅胶体溶液处理后的石英 纤维单丝抗拉强度下降最少。 关键词：石英纤维，自组装，表面处理，二氧化硅 ABSTRACTPREPARATION ABSTRACT PREPARATION OF Si02 PARTICLES AND SELF—ASSEMBLY ON THE SURFACE OF QUARTZ FIBER ABSTRACT Quartz fiber have a wide range of applications in aviation，aerospace， military,semiconductor,high temperature insulation due to its excellent properties in dielectric，heat—resistant．However，the decreasing of mechanical properties of the fiber as the result of heat damage limited its application． There is epoxy resin which has low heat—resistance and can be carbonized at 400—500。C often on the surface of quartz fiber，SO the interracial behavior of the composites will be influenced．In this article，we have prepared the silica particles self-assembly which can improve the mechanical properties of the quartz fiber at high temperature on the surface of quartz fiber after eliminating the epoxy resin—coating． The agents on the surface of quartz fiber were eliminated by using heat treatment and toluene treatment．Tensile strength，XPS，TG—DSC and SEM were used to analyze optimum condition of the surface treated quartz fiber． The results showed that the best method to eliminate the agents on the surface of quartz fiber was heat treated at 400 0C and toluene treated about 9 hours． The monodisperse silicon dioxide spherical particles were synthesized by TEOS，H20，ammonia and ethanol as solvent．The scanning electron 北京化工人学硕lj论文microscopy(SEM)was 北京化工人学硕lj论文 microscopy(SEM)was employed to monitor particle growth and particle size d