单糖HAWORTH式构型识别规则-西华师范大学学报自然科学版.PDFVIP

DOI :10.16246/j.issn.1673 -5072.1998.03.023 　19 3 　　　　 ( )　　　 1998 9 　Vol.19, No.3 　　 Journal of Sichuan Teachers College(Natural Science)　　 Sep.1998 HAWORTH ON THE DISTINCTION RULES OF HAWORTH PROJECTION OF MONOSACCHARIDE 李远军 Li Yuanjun (, 　615022) (Dept.of Chemistr ,Xichang Teachers C ollege, Xichang 　615022) 　　Haw orth , Haworth ———.、Haworth . 　, Haw orth , . 　O629 .112 ABSTRACT　Baced on the invertion of open-chain structures about monosaccharide to ringlike Haw orth projection,theauthor gets the sight-moving method which can be applled to the distinction of all Haworth projections of monosaccharide.The method enables us to determine correctl and easil all Haworth projection t pes and epimers. KEY WORDS　monosaccharide, Haworth projection, method of sight-moving. 1　前　言 ,Fischer Haworth .α,β,, .Fischer Haw orth α,β .,[1～6] , [7] .1990 , . Haw orth ,——— ,. 2 　方法依据 ., , .:.Fischer : 　　1998-01-02. 　19 3 　　　　　　　:Haw orth 337 D-, L-.() D-D-, L-.( ),.:—OH D-, L-.. Haw orth , Hudson , :, Fischer ,. D-,L-.: α-,β-. , Haworth α-,β-. 3 　视线移动法的识别步骤 3 , C—OH ;—CH OH 2 ;. (1)C—OH .Haworth α-,β- D,L , ., : , N .Haworth , —CH OH , —O — 2 , —OHα-,β-.D-L-, ()O—C , O —( ,;, )D-,L-. : 　　　①, —CH OH 2 ,—O ; ②—OH C5 —O —α-; ③:C 2