脉冲电沉积法制备Pd.pdfVIP

32 2 Vol. 32, No . 2 20 11 4 Journal of Hebei University of Science and T echnolo y Apr . 20 11 : 1008- 1542( 2011) 02-0120- 04 Pd-Pt 关 钰, 曹冬梅, 吴世超, 张海黔 ( 南京航空航天大学材料科学与技术学院, 江苏南京 210016) : 氢气易燃易爆, 在工业生产中, 快速准确 对其进行检测是非常必要的采用AAO 模板 法制备Pd-Pt 合金纳米线, 电化学沉积溶液的配制如下: 60 mmol/ L 的PdCl2 + 40 mmol/ L 的 H2 PtCl6 6H2 O + 0. 2 mol/ L 的H3 BO3 , pH 值为5. 9实验参数选择设置为- 0. 4 V ( 1 s) , 0 V( 3 s) , 沉积2 h, 能谱( EDX) 测得Pt 质量分数为30% 左右 : Pd-Pt 纳米线; 电化学沉积法; 多孔阳极氧化铝模板 : O635; TM 555 : A Preparation of Pd-Pt alloy nanow ire by potentiostatic pulse electrodeposition method and its hydro en absorption properties GUAN Yu, CAO Don -mei, WU Sh-i chao , ZHA NG Ha-i qian ( Colle e of Material Science and T echnolo y , Nanjin University of Aeronaut ics and Astronaut ics, Nanjin Jian su 2 10016, China) Abstract : In chemical production, t he in situ rapid accurate and quantitat ive monitorin of hy dro en has important si nificance for safety production because of its inflammable and explosive propert ies. In the study , w e first prepared the Pd-Pt alloy nanow ires w ith AA O as the template by potentiostatic pulse electrodeposition in the solutions of 0. 2 mol/ L H BO containin 3 3 60 mmol/ L PdCl and 40 mmol/ L H PtCl 6H O wit h pH value of 5. 9. For pulsed electrodeposit ion, rectan ular potential 2 2 6 2 pulses w ere used. Durin each pulse, a potent ial of - 0. 4 V versus SCE w as applied for 1 s, follow ed by a potential of 0 V ver- sus SCE bein applied for 3 s, w ith the effect ive elect rodeposition time of 2 h. The ener y spectrum su est ed content of Pt was approx imately 30% . Key words: Pd-Pt