超临界甲醇与松脂反应动力学.pdf

第27 卷第1 期 高 校 化 学 工 程 学 报 No.1 Vol.27 2013 年 2 月 Journal of Chemical Engineering of Chinese Universities Feb. 2013 文章编号：1003-9015(2013)01-0084-06 超临界甲醇与松脂反应动力学 王琳琳, 黄 伟, 陈小鹏, 梁杰珍, 蔡美莲, 谢丹丹 (广西大学 化学化工学院 广西石化资源加工及过程强化技术重点实验室, 广西 南宁 530004) 摘 要：在温度 583 ~623 K、压力 9.2 ~12.1 MPa 和无催化剂的条件下，采用在线采样实验装置进行超临界甲醇与松脂 反应动力学研究。建立了一套超临界甲醇与松脂反应动力学实验方法，利用毛细管柱气相色谱法在线跟踪测定反应体 系浓度随时间的变化关系，按照物质结构和动力学相近原则划分复杂反应体系的集总组分，构建了超临界甲醇与松脂 集总反应网络。以 Matlab 和 Origin 软件估算了动力学模型参数，得到单萜化合物脱氢、加氢、裂解，树脂酸酯化和裂 解的活化能分别为 117.38、76.56、67.62、153.74 和 126.05 kJmol1，所建立的动力学模型与实验数据吻合良好。 关键词：超临界甲醇；松脂；反应动力学；集总 中图分类号：TQ013.2；S789.2 文献标识码：A DOI ：10.3969/j.issn.1003-9015.2013.01.014 The Kinetics of the Reaction of Supercritcal Methanol and Oleoresin WANG Lin-lin, HUANG Wei, CHEN Xiao-peng, LIANG Jie-zhen, CAI Mei-lian, XIE Dan-dan (Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China) Abstract: The kinetics of reaction of supercritical methanol and oleoresin without catalyst at temperature range of 583 K to 623 K and under pressure of 9.2 MPa to 12.1 MPa was investigated by an experimental device with online sample analysis. A set of experimental methods for studying the kinetics of the reaction of supercritical methanol and oleoresin was established. The changes of the component concentration with reaction time were measured by tracking analysis of the capillary gas chromatograph. According to the principle of having