高岭土界面电化学性能及其对重金属的吸附研究.pdfVIP

( ),2014,45(5):675-679,685 VOL.45 NO.5 2014 山东农业大学学报 自然科学版 Journal of Shandong Agricultural University (Natural Science Edition) doi:10.3969/1000-2324.2014.05.008 高岭土界面电化学性能及其对重金属的吸附研究 张树芹,路福绥,姜 林 山东农业大学 化学与材料科学学院, 山东 泰安 271018 摘 要: 分别采用质量滴定法(MT) 、电势滴定法(PT)测定了荷结构负电荷的高岭土的零电荷点，MT法与PT法的实验 结果分别为：3.70±0.05和2.16，质量滴定法结果明显高于电位滴定法。结合表面络合模型推算了表面位密度(Ns)及各 int int 2+ pK pK pK Pb pH 特征络合平衡常数 、 a1 、 a1 。研究 在高岭土上的吸附性能，考察 值、离子强度等因素对吸附量 的影响，并探讨了吸附机理。高岭土吸附Pb2+ 的动力学曲线符合准二级动力学方程，吸附等温线符合Langmuir方程。 Pb2+ 同时以内层络合和外层络合形式吸附，其相对量与pH有关；在pH小于4和大于8的范围内，内层络合物为主，而 pH 4 8 在 ～ 范围内外层络合物比例增大。 关键词: 质量滴定; 电位滴定; 高岭土; Pb2 + ; 吸附 中图法分类 :O647 文献标识码: 文章编 :1000-2324(2014)05-0675-05 Interface Electrochemical Characteristics in Kaolinite and Its EffectontheAdsorptionPropertiestoHeavyMetal ZHANG Shu-qin*, LU Fu-sui, JIANG Lin CollegeofChemistryandMaterialScience,ShandongAgricultural University, ShandongTaian271018, China Abstract: The point of zero charge of the kaolinite with structural negative charge was measured by mass titration and potentiometric titration. Result shows that the rage of PZC for MT method was 3.70±0.05 which was significantly higher than PT method (2.16). According to the surface complexation model the surface site density and intrinsic surface reaction equilibrium constants (pK 、pK int 、pK int 、) were calculated. Adsorption properties of Pb2 +on kaolinite were studied, the a1 a1 influence of solution pH and ion strength on the adsorption of Pb2+ were investigated, and the adsorption mechanism was discussed. The adsorption kinetics of Pb2+ on kaolinite can be described by the pseudo-second-or