铁酸铋功能陶瓷薄膜的液相自组装制备.pdf

· 1824 · 硅 酸 盐 学 报 2009 年 第 37 卷第 11 期 硅 酸 盐 学 报 Vol. 37 ，No. 11 2 0 0 9 年 1 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY November ，2009 铁酸铋功能陶瓷薄膜的液相自组装制备 谈国强，博海洋，苗鸿雁，夏 傲，贺中亮 (教育部轻化工助剂化学与技术重点实验室，陕西科技大学，西安 710021) 摘 要：利用自组装单层膜技术，以三氯十八烷基硅烷(octadecyl trichlorosilane，OTS)为模板，以硝酸铋和硝酸铁为原料，在玻璃基片上成功制备了 铁酸铋(BiFeO3) 晶态薄膜。采用接触角仪测量了紫外光照射后OTS 单层膜的亲水性。通过 X 射线衍射、扫描电镜和能谱仪等表征了 BiFeO3 薄膜的物 相、表面形貌及微观结构。结果表明：紫外光照射使 OTS 单层膜由原来的强疏水性转变为良好的亲水性，说明 OTS 自组装膜层表面已被羟基化。在 70 ℃沉积 8 h 并经 600 ℃退火 2 h 制备的 BiFeO3 薄膜结晶良好，薄膜样品的表面平整，厚度较为均匀，薄膜厚度约为 100nm 。 关键词：自组装单层膜；铁酸铋；薄膜 中图分类号：TB43 ；TQ135.3+2 文献标志码：A 文章编号：0454–5648(2009)11–1824–05 PREPARATION OF BiFeO THIN FILM BY A SELF-ASSEMBLED MONOLAYER TECHNIQUE 3 TAN Guoqiang，BO Haiyang ，MIAO Hongyan ，XIA Ao ，HE Zhongliang (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xi’an 710021, China) Abstract: BiFeO3 thin films were successfully prepared on glass wafers with a self-assembled monolayer (SAM) technique using Bi(NO ) and Fe(NO ) as raw materials and octadecyl trichlorosilane (OTS) as stencil. The hydrophilicity of ultraviolet 3 3 3 3 (UV)-irradiated OTS monolayer film was measured by a contact angle measurement system. The phase composition, surface mor- phology and microstructure of the films were characterized by X-ray diffraction, scanning electron microscopy and energy dispersive spectrometry. The results show that the OTS–SAM film surface is transformed from a strong hydrophobic surface to a su- per-hydrophili