电感耦合等离子体质谱法测定葡萄酒中32种元素的含量.PDF

7 12 Vol. 7 No. 12 2016 12 Journal of Food Safety and Quality Dec. , 2016 32 * 廖红梅 , 覃 然, 陈 璐, 赵永锋 (, 530028) 摘 要: 目的 (Inductively coupled plasma mass spectrometry, ICP-MS) LiBeBNaMgAlPKMnFeNiCoCuZnGaAsMoCdSnSbCsBa HgTLCaVCrSeRbSrPb Sb 32 方法 , ICP-MS 32 1550 W, 10 min 6%( )结果 , CaMgK RbPCu 86 ~118 , 0.4%~4.9%(n=10), 0.005~4.00 μg/L结论 ICP-MS , 关键词: -; ; Determination of 32 kinds of elements in wine by inductively coupled plasma-mass spectrometry * LIAO Hong-Mei , QIN Ran, CHEN Lu, ZHAO Yong-Feng (Technical Center of Guangxi Entry-Exit Inspection and Quarantine Bureau, Nanning 530028, China) ABSTRACT: Objective To establish a method for the determination of 32 kinds of inorganic elements including Li, Be, B, Na, Mg, Al, P, K, Mn, Fe, Ni, Co, Cu, Zn, Ga, As, Mo, Cd, Sn, Sb, Cs, Ba, Hg, TL, Ca, V, Cr, Se, Rb, Sr, Pb and Sb etc. in wine by inductively coupled plasma mass spectrometry (ICP-MS). Methods Wine samples were detected by ICP-MS after direct sampling. Selecting radio frequency (RF) power of 1550 W, the matrix interference was reduced through online introducing internal standard solution containing 6% ( V:V) ethanol and signal collection every 10 min. Results Wine contained a variety of trace elements, among the content of Ca, Mg, K, Rb, P and Cu was h