疏水链长对聚氧乙烯失水山梨醇脂肪酸酯界面扩张-IngentaConnect.PDF

物理化学学报(Wuli Huaxue Xuebao) 322 Acta Phys. -Chim. Sin. 2015, 31 (2), 322-328 February [Article] doi: 10.3866/PKU.WHXB201412012 疏水链长对聚氧乙烯失水山梨醇脂肪酸酯界面扩张流变性质的影响 李 明1,2 曹 冲1 熊可洁1 杜凤沛1,* 1 2 ( 中国农业大学理学院应用化学系, 北京100193; 黑龙江省农业科学院农药应用研究中心, 哈尔滨150086) 摘要: 利用悬挂滴方法研究了系列聚氧乙烯失水山梨醇脂肪酸酯(TweenX)在正癸烷-水界面的扩张流变性 质. 实验结果表明, 疏水烷基链长较短的Tween20 分子在界面上吸附量较大, 分子排列更紧密, Tween40 和 Tween60 具有大致相同的“有效截面积”, 导致饱和吸附时界面张力(γcmc) 比较接近. TweenX浓度大于临界胶束 浓度(cmc)时, 由于Tween20 分子排列的更加紧密, 模量和弹性大于Tween40 和Tween60. 当TweenX 的疏水 烷基链长达到一定长度时, TweenX 的界面膜性质受疏水链长的影响减弱, Tween40 和Tween60 的扩张参数相 差不大. 关键词: 聚氧乙烯失水山梨醇脂肪酸酯; 疏水链长; 界面; 扩张模量; 相角 中图分类号: O647 Effect of Hydrophobic Chain Length on the Interfacial Dilational Rheological Properties of Polyoxyethylene Sorbitan Fatty Acid Ester LI Ming1,2 CAO Chong1 XIONG Ke-Jie1 DU Feng-Pei1,* 1 ( Department of Applied Chemistry, College of Science, China Agriculture University, Beijing 100193, P. R. China ; 2Research Center of Pesticide Application, Heilongjiang Academy of Agricultural Sciences, Harbin 150086, P. R. China) Abstract: The dilational rheological properties of a series of polyoxyethylene sorbitan fatty acid surfactants (TweenX) at the decane/water interface have been investigated using the drop shape analysis method. The experiment results showed that larger quantities of the Tween20 molecules with shorter hydrophobic chain lengths were adsorbed at the interface because they could arrange more closely. Tween40 and Tween60 molecules had simila