厌氧膜生物反应器中亲疏水性有机物的膜污染特征-北京玛格泰克科技.PDFVIP

中国环境科学 2018,38(7) ：2471~2476 China Environmental Science 厌氧膜生物反应器中亲疏水性有机物的膜污染特征 余智勇 1,2,文湘华 1* (1.清华大学环境学院,北京 100084 ；2. 中国华能集团清洁能源技术研究院有限公司,北京 102209) 摘要：采用树脂吸附脱附的方法对厌氧膜生物反应器(AnMBR) 中溶解性微生物代谢产物(SMP)的 6 种亲疏水性有机物进行了分离,其中,亲水中性物质 是 SMP 的主要成分, 占总有机物的 74.84%.多糖、蛋白质和腐殖质类物质在亲疏水性有机物中均有分布.采用恒压死端过滤的方式对比分析了 6 种亲疏 水性有机物的微滤特性,发现在 TOC 浓度相同的条件下,亲水性碱(HIB)是造成膜通量下降最快的物质,其次是亲水中性物(HIN)和疏水性酸(HOA),膜通 2 量下降速率与有机物平均粒径呈指数相关关系(R =0.9965).采用过滤模型对微滤过程进行拟合,HOA、HIN 和 HIB 的过滤过程分别符合标准堵塞模型、 中间过滤模型和滤饼过滤模型的特征,与其粒径分布特征相对应.试验进一步对比了亲疏水性有机物污染层的可逆性,结果表明 HIN 造成的膜污染不易 通过物理反冲洗得到恢复. 关键词：厌氧膜生物反应器；溶解性微生物代谢产物；亲疏水性有机物；膜污染；微滤特性；粒径 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2018)07-2471-06 Fouling of microfiltration membranes by hydrophilic and hydrophobic organic fractions in Anaerobic membrane bioreactors. YU Zhi-yong1,2, WEN Xiang-hua1* (1.School of Environment, Tsinghua University, Beijing 100084, China ；2.Huaneng Clean Energy Research Institute, Beijing 102209, China). China Environmental Science, 2018,38(7)：2471~2476 Abstract ：In this study, the soluble microbial product (SMP) in an anaerobic membrane bioreactor (AnMBR) was fractionated into ® six kinds of hydrophilic or hydrophobic fractions through a sequence of adsorption/desorption using DAX-8, Amberlyst 15 and ® Amberlyst A21 resins. The hydrophilic neutrals (HIN) was found to be the major component in the SMP, accounting for 74.84% in terms of the total organic carbon (TOC). Polysaccharides, protein, and humic substrates were identified in all the six types of organic fractions. In order to further understand the membrane fouling mechanism of different organic fractions, the fouling propensity was evaluated through a series of batch microfiltration experiments with a stirred dead-e