刚玉质浇注料孔结构的分形特征-硅酸盐学报.PDFVIP

· 730 · 硅 酸 盐 学 报 2010 年 第38 卷第4 期 硅 酸 盐 学 报 Vol. 38 ，No. 4 2 0 1 0 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2010 刚玉质浇注料孔结构的分形特征 朱伯铨，方斌祥，李享成，姜 晓 (武汉科技大学，耐火材料与高温陶瓷国家重点实验室培育基地，武汉 430081) 摘 要：分别以铝酸钙水泥和ρ–Al O 为结合剂，制备了2 种刚玉质浇注料。利用Menger 海绵体模型和压汞试验数据，探讨了浇注料经不同温度热 2 3 处理后的孔结构分形特征。结果表明：刚玉质浇注料的孔结构与结合系统关系不大，其临界孔径为 1 μm ，显示出双重分形特征，微孔区间(≤1 μm) 的分形维数小于大孔区间(1 μm) 的；热处理温度对浇注料孔结构分形维数的影响比微粉填充的影响更为显著。在微孔区间，自由水蒸发导致的分形 维数大于结晶水脱失导致的，并远远大于烧结导致的；在大孔区间，烧结导致的分形维数则大于气泡导致的分形维数。 关键词：刚玉质浇注料；孔结构；分形维数；热处理；临界孔径 中图分类号：TQ175 文献标志码：A 文章编号：0454–5648(2010)04–0730–05 FRACTAL CHARACTERISTICS OF PORE STRUCTURE OF CORUNDUM BASED CASTABLES ZHU Boquan ，FANG Binxiang ，LI Xiangcheng ，JIANG Xiao (State Key Laboratory Breeding Base of Refractories and Ceramics, Wuhan University of Science and Technology, Wuhan 430081, China) Abstract: Two corundum-based castables were prepared using calcium aluminate cement and ρ–Al O as the binder, respectively. 2 3 Fractal characteristics on the pore structure of castables heat-treated at different temperatures were investigated by means of Menger sponge model and mercury intrusion porosimetry. The results show that the pore structure of corundum-based castables is not related to the bonding systems and exhibits double fractal characteristics with the critical pore size of 1 μm. Fractal dimension of the micro pore size interval ( ≤1 μm) was smaller than that of the large pore size interval (1 μm). Influence of heat treatment temperature on fra