介孔材料的掺杂及薄膜的制备-应用化学专业论文.docxVIP

摘 摘 要 本逢文分为嚣邦分： 1．采用水热合成法，在碱性条件下湖备了MCM，41和MCM．48介 孔材料，并对台成的介孔材料进行了众属掺杂(篡中MCM一41掺杂了 Al，MCM．《8掺杂了Ce、Cu、Z骢、AI)。透过粉末XRD、红步}光谱、 {豪温N2蔽瓣一瓣瓣蒎术、紫终疆反瓣蔽收光谱霹翻备翁菇燕送露了表 征。结祟表明：掺杂的锅进入了MCM．41的骨架中，其中Al的醚位状 态随着掺杂激的不同丽不愿，量多对怒以瞪配位遴入MCM-41鹪嚣絮 的，显少时则是以六配位处于MCM一41的骨架外。巍于MCM．48的合 袋秘瑾还欠宠饕，合戒簸件与MCM-41裰融较复杂，掺杂魏金嚣离子 只有部分进入骨架中，需继续探索MCM．48合成和掺杂的最佳条件。 2+在酸性条件下，乙醇为溶剂的体系中，以预处理的载玻片、普通 玻璃为鏊底，通过浸渍撼弛法裁套出分孔氧纯硅薄膜，鞭究了浸涂法分 魏Si02簇黪翻各工艺，著考察了众多影嫡溶黢瑷爨翡因素鼹或袋藤董 的影响。结构测试结果表明：合成的薄膜均匀、违续且孔道平行予蒸底 表面；基底的性质对奔琵膜的生长存～定程度的影滴作矮。机槭经能测 试结聚表明：膜具有一定酌机械强度，是一矛申很有应用裁景的介孔薄膜 榜瓣。 关键谰：介孔MCM．41 MCM．48 Si02薄膜 ABSTRACTnlere ABSTRACT nlere are two parts in this dissertation： 1．MCM一41，MCM一48，A1-MCM-41and M(Ce，Cu，Zn，A1)-MCM一48 material were prepared by the hydrothermal method。By means of powder X-ray diffraction，low-temperature nitrogen absorption—adsorption technique and ultraviolet difluse reflectance spectroscopy，the samples were characterized．The results showed that the metal ion was successfully incorporate in the framework of mesoporous material．The COOrdinated state of the aluminum with the variety of the amount but varies．The quality of the aluminum iS big．the atoms are present with a 4一COOrdinated in the framework of sample．Otllerwise a 6一coordinated out of the framework of sample．强e UV results showed that some metal ions could enter the framework of MCM-48．We should change the conditions to go on more research． 2．Mesoporous silica thin mfinbranes have been produced by hydrothermal deposition method in non-aqueous solvent．By means of XRD． TEM。SEM and IR spcctroscopvl the structure of the films WaS characterized．The results showed th毹the membranes had the structure of mesoporous MCM-41 with the pore channel of membrane paralleled to the substrate and different substrate had certain effcct on membrane growth． The mechanical character of membrane WaS Studied on．The results showed the membrane had good wear-resisting property and intense adhesive power． Keywords：Mesoporous Materials，MCM-41，MCM-‘|8，Si02 Membrane II 长券理工犬学硕士学位论文原创性声