基于并噻吩二羧酸配体的金属有机框架的合成、结构和性质分析-有机化学专业论文.docxVIP

聊城大学硕士学位论文 聊城大学硕士学位论文 PAGE PAGE iii Abstract Metal-Organic Framework (MOFs) materials are receiving more and more attention in recent years, due to their potential applications in many fields, such as catalysis, sensing, gas separation and adsorption, molecule identification, drug transportation, electronics as well as magnetism. Current research mainly focuses on the rational design and synthesis of novel MOFs with unique structures or particular functions. To further explore relationships between syntheses, structures and properties, we selected an S-containing carboxyl ligand, 3,4-dimethyl[2,3-b]thiophene-2,5-dicarboxylic acid (H2DMTDC). Based upon this ligand, a series of coordination polymers were obtained through reactions with transition metals or rare-earth metals under solvothermal conditions. The research includes: Transition metal complexes based upon H2DMTDC and N-containing ligands: syntheses, structures, luminescent and magnetic properties Six complexes were solvothermally synthesized, namely, [Zn(DMTDC)(bpt)(H2O)]n (1), {[Zn(DMTDC)(5,5-dmbpy)]·0.5DMF·1.5H2O}n (2), [Zn(DMTDC)(1,3-bimb)]·2DMF·H2O}n (3), [Zn2(DMTDC)2(bpp)]n (4), [Co(DMTDC)(bpe)]n (5), and [Co2(DMTDC)2(bpp)(DMF)2(H2O)]·H2O}n (6) (bpt = 4-amino-3,5-bis(4-pyridyl)-1,2,4 -triazole, 5,5′-dmbpy = 5,5′-dimethyl-2,2′-bipyridyl, 1,3-bimb = 1,3-bis(imidazol-1ylmethyl) -benzene, bpe = 1,2-Bis(4-pyridyl)ethylene, bpp = 1,3-di(pyrid-4-yl)propane). Complexes 1 and 2 are 1-D linear and zigzag chains with different supramolecular structures. In complex 1, adjacent chains form zipper-like structures through N–H?N interactions. In complex 2, however, chains in adjacent layers are stacked in an unusual unparallel level through C–H?O interactions. Complex 3 features a highly corrugated 2-D (4,4) layer and the layers are penetrated byeach other to give 3-D polycatenations. Right- and left-handed helical Zn-bimb chains are arranged alter