基于苝的衍生物的自组装体系的构建表征及性质-材料加工工程专业论文.docxVIP

基于j芭的衍生物的自组装体系的构建表征及性质 基于j芭的衍生物的自组装体系的构建表征及性质 摘要 本论文从新的有机功能分子体系的设计合成出发，借助氢键和金属 配位构建了两类功能有机分子的自组装体系，并研究了它们的光物理性 质和聚集态结构，又设计合成了一个双荧光分子开关和逻辑门。 设计合成了以芄二酰亚胺为主体的氢键自组装和金属配位超分子 体系，得到了不同聚集态形貌的超分子纳米结构。首先，我们合成了含 有二酰胺基吡啶单元的花衍生物，利用二酰胺基毗啶单元的三点氢键和 范平面之间的堆积作用，构建了花氢键自组装超分子纳米纤维。其次， 我们设计合成了含有，一二酮单元的花衍生物，利用二酮单元与金属的 配位和花平面之间的堆积作用，构建了花金属自组装超分子纳米球。 设计合成了一个简单的“折页”状双荧光分子开关，它在不同的外 界输入下可以经历可逆的构象变化，并且在不同的状态下显示不同的荧 光信号。在自由状态下，两个芘平面之间由于强的丌一Ⅱ作用，形成激 发态缔合物，显示单一的“excimer”发射(470hm)。当加入酸或者金 属离子时，两个芘平面会分开，显示强的单体发射(370nm)。这个过程 是完全可逆的，而且信号输出是可读的。 发现了基于藐一咔唑二元供受体系的聚集诱导的荧光发射性能。 关键词： 自组装， 氢键， 金属配位，逻辑门 FABRACATION FABRACATION A ND PROPERTIES 0F SELF．ASSEN住；LY SYSTEMS CONTAIN PERYLENE DEIU、f【舡IVES ABSTRACT This thesis presents the studies on synthesis and characterization of novel self-assembly systems based on functional organic molecules，as well as the dual fluorescent molecular switch and’logic gate．The main conclusions are as follows： Two novel self-assembly systems based on linear perylene derivative were prepared through hydrogen bond and metal coordination interactions． Firstly，we synthesized BDAP(bearing perylene diimide unit and diacylaminopyridine unit)，which Can form well—defined 1D long fibers aggregate state structure by virtue of the combination of 71；-兀stacking and hydrogen bond induced self-assembly．In addition，we synthesized DP and DPD(bearing perylene diimide and fl-diketone groups)and their corresponding copper(ID complexes，which Can form isolated and consecutive nano-particles，respectively． We designed a particularly simple dual-mode fluorescent molecular switch，which could undergo reversible conformation transformation in response to external inputs such as protons and metal ions，each state corresponding to a specific fluorescent emission peak．The molecular switch 2,6一di(pyrenemethylamine—methyl)一pyridine [PPP] exhibits distinct conformation conformation and fluorescence under different inputs．Remarkably,when formed a film on the quartz slide，the acid induced fluorescent switch acts