基于光电传感原理的探针构建及其分析检测应用-物理化学专业论文.docxVIP

AbstractElectrochemiluminescence(ECL)not Abstract Electrochemiluminescence(ECL)not only has the advantages of chemiluminescence，but also it has the advantages of high sensitivity,large measuring range，easy operation and high degree of automation．At present，it has received widespread attention．Therefore，they have potential applications in many important analytical science fields，such immunoassay and environmental，chemical measurements in the agriculture and food industry,drug analysis and molecular diagnosis of disease and on．Due to the nanomaterial of large specific surface chemical reactivity and size effect，nanomaterials have been widely used to immobilize matericals in the solid．state EeL sensor．ECL based nanomaterials demonstrating very promising properties of signal amplification labels in electrochemical applications． Fluorescence technology has many advantages in the environmental testing，life sciences and disease diagnosis，due to its noninvasive and high selectivity．Now,it has been recognized effective and general．In this paper,silicon dioxide nanoparticles，gold Nanoparticles and nation were applied to fabricate the EeL A highly selective and ratiometric ESIPT-based fluorescent probe for fast monitoring of hydrazine in aqueous solution in gas state was designed and synthesized．The major contents in this thesis described follows： (1)A low—cost and convenient Ru(bpy)3H7Au／HNTs／Ti02／Nafion based ECL was constructed in the present work．Electrochemical and ECL behaviors of Ru(bpy)32+／Au／HNTs／Ti02／Nafion modified electrodes’were investigated．TPA test shows good electrochemical luminescence properties，and the electrochemical luminescence signal amplification well，fully embodies the superiority of AuNPs／HNTs／Ti02 composites and its important role in the signal amplification．The synthesized ECL may be applied in chemical and biochemical analysis in the future． (2)Based benzothiazole compounds(HMBT)，an ESIPT based fluorescent probe EPH of NH2NH2 was