碱金属铌酸盐系无铅压电陶瓷的性能研究-材料学专业论文.docxVIP

摘要本文运用熔盐合成工艺制备了Na 摘要 本文运用熔盐合成工艺制备了Na o 5K o 5Nb03(简称NKN)无铅压电陶瓷，研 究了熔盐量和合成温度对性能的影响，并确定最佳的工艺参数为：熔盐量与原料比为 8wt％，合成温度为800℃和保温时间2h。本文还研究了Sb5+和Li+离子分别掺杂对 Na o 5K 0 5Nb03系统的压电性能、介电性能和机电性能的影响及变化趋势，分析了产 生这些现象的原因，为进一步对基础系统的掺杂改性研究提供了依据。实验结果表明： 当Sb5+含量为8mo!％时，烧结温度为1 100。C时，具有较好的综合性能：当Li+含量为 6m01％时，系统组成位于准同型相界处(Morphotropic Phase Boundary)，烧结温度为 1100(2时，可以得到一种综合性能较好的材料。sb”和Li+掺杂均使材料表现出了介 电驰豫现象。最后，还研究了(Nao 5Ko 5)094 Li006(Nb092Sbo．os)03系统的性能，sb”和 Li+的共同掺杂使试样的致密度大大提高，介电驰豫性大大减弱，综合性能大大改善， 同时也研究了氧化铜对NKN—LS陶瓷性能的影响。 本文通过扫描电子显微镜(sEM)观察试样表面和断面处的显微结构，使用x射 线衍射(XRD)对合成粉末的相组成及相含量进行了分析，并对固相合成法和熔盐合 成法作了比较，研究了烧结温度对NKN陶瓷性能的影响。 关键词：无铅压电陶瓷熔盐法掺杂XRD SEM介电压电性 ABSTRACTThe(Na0 ABSTRACT The(Na0 5K0 5)Nb03 lead free piezoelectric ceramics was prepared and its powder was calcined by molten salt synthesis and the influence of molten salt contents and the synthesizing temperature were studied，the best processing parameters Was conformed：the ratio of molten salt cement and raw material was 8w1％and synthesizing temperature is 800℃for2h． The effect of Sb5+and Li+substituting content on the piezoelectric，dielectric and electromechanical properties ofsodium potassium niobate lead free piezoeleewic ceramics Was also studied and its result provided the foundation for the funller experiments．The results show that when S矿+substituting content is 8m01％and sintering temperature is 1100。C，good comprehensive properties Can be obtained；when Li substituting content is 6mol％and sintering temperature is l 100(2．which is located in morphotropic phase boundary(MPB),good dielectric and piezoelectric properties Can be observed：Sb”and Li+substituting sodium potassium niobate lead free piezoelectric ceramics all exhibit relaxer behavior；Finally the properties of(Nao 51(0．5)094 Li006(Nb092Sb000 03ceramics and the effect of CuO was studied．It Was found that the densification of Sb5+and Li+ co-doped sample Was enhanced，relaxor behavior Was weakened and the performance was improved． The scanning electronic microscope(SEM)and X—ray dif