碱矿渣基地质聚合物的制备及其高温性能研究-材料化学工程专业论文.docxVIP

时的SEM能清楚地看到物相呈晶体的形貌；另外随着煅烧温度的增加，碱 时的SEM能清楚地看到物相呈晶体的形貌；另外随着煅烧温度的增加，碱 矿渣基地质聚合物材料的平均孔径先增大后减小。在600。C时，碱矿渣基地 质聚合物材料的平均孔径最大，为18．3 1 nlrl；在200℃时，碱矿渣基地质聚 合物材料失重速度最快；在800℃时，碱矿渣基地质聚合物材料质量基本保 持不变。当煅烧温度为1100。C时，碱矿渣基地质聚合物材料的抗压强度为 51．1 MPa，线收缩率为7．64％，平均孔径为5．69 nlTl，结晶相主要是黄长石， 此时由SEM能清楚地看到物相呈晶体的形貌。当煅烧温度为1400。C时，碱 矿渣基地质聚合物材料的抗压强度为77．2 MPa，线收缩率为10％左右，平均 孔径为3．24 nlTl。 综合来看，本实验制备的碱矿渣基地质聚合物材料具有优良的耐高温 性能，在高温下仍能保持足够的强度，缺点是高温下线收缩率较大，这有 待进一步探讨。 关键词：碱矿渣基地质聚合物制备高温煅烧物相 II 万方数据 THE THE PREPARAT蟹ON AND HIGH TEM咿ERATURE PERFoRM睑NCE RESEARCH oF ALKALI SLAG BASE GEoPoLYM匝R M陵TERIAI。S AB STRACT Geopolymer is a type of altmainosilicate inorganic polymer material consists of tetrahedral[S i04]4。and[A104]孓units，which is of amorphous to semicrystalline．Due to the geopolymer material has excellent performance such as high strength，simple production process，less pollution，energy conservation， good compactness，high temperature resistant and anti·corrosion performance，it is widely used in a range of areas inc lud ing c ivil engineering materials and rap id repair materials，geological polymer matrix composites，high quality geopolymer coating,toxic waste and waste solid sealing materials，porous materials，and SO on． In this paper,considering mechanical properties and setting time as the main evaluation index，the slag and liquid water glass which Was added by KOH to adjust the modulus were used as the main raW materials to prepare the alkal i shg base geopolymer material of excellent mechanical properties and workability,with KH2P04 as the retarder．By single factor experiments，this paper discmsed how the exciting agent dosage，water cement ratio and modified waterglass modulus affected the performance of the alkali slag base geopolymer material,on the basis above，the retarder KH2P04 was introduced to improve the workability of alkali s lag base geopolymer material．And the optimum parameter of the alkali slag geopolymer material which were cured at different temperature was determined：the modified waterg