碱土金属硫化物纳米晶的制备及其性质的研究-应用化学专业论文.docxVIP

Abs Abstract Shanghai Normal University Master of Philosophy 万方数据 万方数据 nanocrystals’morphology was discussed, the experimental results showed that spherical, concave cube and ellipsoid SrS nanocrystalline was prepared by added different alkali metal ions (Li+, Na+, K+), Additionally, alkali metal ions played a significant role in the control of these NC morphologies and size. the SrS:Li, SrS:Na, SrS:K nanocrystals shape changed from sphere to concave-cubic and then to ellipsoid. We also studied the luminescence spectra of different alkali metal-doped SrS nanocrystals at a different Mn2+ion concentration. We used the same method to prepare different morphologies of CaS nanocrystals, and explored the effect of alkali metal ions on CaS:Mn fluorescence performance. 2, Using alkali metal oleate as the metal source, dodecyl mercaptan as a sulfur source , all alkaline earth metal sulfide(MgS, CaS, SrS, BaS) were successfully prepared by Single-source precursor method. Meanwhile, we took CaS and SrS as example, the effect of dodecanethiol/amine ratio on dispersible of nanoparticles was discussed. the influence of Mn2+ and Cu+ on CaS, SrS nanocrystals luminescence properties was also studied. Keywords: alkaline earth metal sulfides; CaS; SrS; nanocrystalline; fluorescent material Paper type: research report IV 上海师 上海师范大学硕/博士学位论文 目录 目录 第一章 绪论....................................................................................................................................1 1.1 金属硫化物简介...................................................................................................................... 1 1.2 金属硫化物纳米晶液相合成............................................................................................... 1 热注入法(Hot-injection) 1 单源前驱体热分解法(Single-source precursor) 2 溶胶-凝胶法(sol-gel method) 3 HYPERLINK \l _TOC_250002 共沉淀法(co-precipitation method) 3 HYPERLINK \l _TOC_250001 水热法(Hydrothermal Synthesis) 3 HYPERLINK \l _TOC_250000 溶剂热法(Solvothermal Synthesis) 4 液固相转移