碱土元素与铕共掺杂钒酸钇发光材料的制备及性能研究-材料学专业论文.docxVIP

摘 摘 要 万方数据 万方数据 摘 要 本文采用以乙二醇（EG）为溶剂和聚乙烯吡咯烷酮（PVP）为表面活性剂 的溶剂热法在 150 oC 下反应 10 h 制备高分散、类球形亚微米的碱土元素与铕共 掺杂钒酸钇 YVO4:Eu3+, M2+ (M = Mg, Ca, Sr, Ba)发光材料，并对其进行 XRD 晶 体结构分析、SEM 表面形貌分析和 PL 谱光致发光性能分析。掺杂碱土元素后， 其 XRD 图谱与标准四方相 YVO4 晶体图谱相吻合，且没有杂相出现，同时对其 形貌也没有较大的影响。碱土元素掺杂后，YVO4:Eu3+, M2+荧光粉对紫外光区 V-O 电子迁移带的吸收有明显增强。同样与 YVO4:Eu3+荧光粉相比，掺杂碱土元 素能有效提高其发光强度约 200 %。并研究了掺杂元素（Ba2+或 Sr2+与 Eu3+）间 的相互作用并对发光强度的影响，当固定其中一个的掺杂浓度时，会出现一个 相对应的淬灭浓度。最后，探讨了热处理对 YVO4:Eu3+, M2+ (M = Sr, Ba)荧光粉 晶体结构、表面形貌和发光性能的影响。热处理过程既提高了晶体的结晶性又 降低了晶体内部缺陷，进而提高发光效率。 关键词：碱土元素；铕；钒酸钇；发光性能 I AB ABSTRACT ABSTRACT The uniform and dispersed quasi-spherical alkaline earth metals and Eu3+ co-doped yttrium vanadate (YVO4:Eu3+, M2+ (M = Mg, Ca, Sr, Ba)) sub-micro luminescence material were synthesized by a facile low-temperature solvothermal process using EG as solvent in the presence of PVP under 150 oC for 10 h. X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL) spectroscopy were used to characterise the microstructure, morophology, and luminescence properties of the as-prepared samples. The XRD patterns of YVO4:Eu3+ doped with Mg2+, Ca2+, Sr2+ and Ba2+ ions exhibited the characteristic peaks of pure tetragonal YVO4, which were well indexed to the values of the standard card (JCPDS No. 17-0341), and no extra phase related with dopant components was detected. Compared with that of YVO4:Eu3+ phosphor, the morphology of YVO4:Eu3+ phosphor had not obvious change after doping with alkaline earth dopants. Obviously, the absorption of V-O charge transfer band in the UV region after doping with the alkaline earth metals enhanced. Similarly, in comparison with those of YVO4:Eu3+ phosphor, the intensity of red emission had greatly enhanced up to about 200% for YVO4:Eu3+ co-doped with the alkaline earth metals. The effect of mutual action and the dopants (Ba2+ or Sr2+ and Eu3+) concentrations on luminescence properties was studied, and this indicated that each of the codopants i