渐变型塑料光纤预制棒的制备与工艺研究-材料学专业论文.docxVIP

哈尔滨理T大学T学硕{：学位论文渐变型塑料光纤预制棒的制备与工艺研究 哈尔滨理T大学T学硕{：学位论文 渐变型塑料光纤预制棒的制备与工艺研究 摘要 1964年，美国拄邦公司首先成功磷镪了除跃墅塑睾耳光纤，并授浚巍晶 化。其后，通过二十多年的研究，在降低塑料光纤损耗方面取得了很大的成 王鸯。1982年，曩本庆痤失学的koike等人善先爝赛霆。凝黢法磺裁了梯度型 塑料光纤，提高了塑料光纤的传输带宽，有效地解决了信息传输的瓶颈问 题。 本文通过对骥料光纤的损耗、色散与带宽进行详细讨论，分析了梯度型 塑料光纾在带宽方面无法比拟的优点。 梯度溅塑料光纤翻备方法主婺有两种：直接挤出法翔预制棒拉纤法。 预制棒拉纤法的关键技术是预制棒的制备，我国在预制棒制备工艺lj仍 然存在校多逸题。本漂瑟主要磺究鹾甲鏊蠢浠酸攀蘸为纂矮，溪苯为离辑象 率掺杂剂，用界耐，凝胶法制备梯度型塑料光纤予员制棒，通过改变原材料配 跑、醴及滋凄、藤强等嚣素，分孝秀气渔耱真空逡存在豹骧困势提出褥决方 案；通过调节链转移剂的含量，控制聚合物分子量分布以及分子量分布宽 度，献丽控制预铡捧的玻璃化转变澡度(黝，使铡蛋的转具有是好的拉缝性 能，以及所拉出的纤维其有较高的强度：另外对预制棒折射率的形成机理进 行模拟，并用空蚓滤波法融折射率进行测量；通过对不同溴苯浓度的样撼拆 莉率测试绪栗分轿，褥密澳苯对拆射率彩确只与溴苯的橱始浓壤有关。最后 通过大量试验确定制备基本无缺陷的预制棒的工麓条件以及最俄原材料配比 方案。 美键调塑辩光纤：予夏铡梅：撬慰攀；带瓷 ，， ，， 篁尘堡些三垒兰三兰丝!i兰竺丝塞 STUDY oN PREPARATIoN oF GRADED INDEX PERFORM ROD Abstract In 1 964，American DuPont firstly succeeded in developing the SI—type plastic optical fiber，and commercialized it quickly．Thereafter，through more than 20 years’research，great SUCCESS had been made in reducing the transmission loss of plastic optical fiber．In I 982，koike etc of Japanese Keio Universit37 firstly developed GI—type plastic fiber by the interface—gel method，having improved the transmission bandwidth of the plastic optical fiber，and effectively settled the bottleneck problem of information transmission． {n this dissertation，through discussing the transmission lOSS，optical dispersion and bandwidth of plastic optical fiber in detail，we have analyzed the incomparable advantages of GI poF in bandwidth． There are two ways for the preparation of GI—type plastic optical fiber：directly extruding and fiber-drawing from preform rod． The key technique of the latter method is the preparation of the preform rod． but we still have many problems with the technique of its preparation at home．In this subject，we have carried on research its preparation by interface—gel method taking MMA as base-material，taking BB as the dopant of high refractive index．Through changing the contents of raw materials，temperature and pressure， we laave analyzed the