界面引发微乳液聚合-高分子化学专业论文.docxVIP

AbstractThree Abstract Three series of investigations were carried out to gain insight into the characteristics of interfacial—initiated microemulsion copolymerization．There are two main aims of these investigations：one is to demonstrate that interfacial．initiated micmemuslion polylnerization facilitates the copolymerization of water-soluble monomer with oil—soluble monomer,and the other is to investigate the possibility to control the morphology and structure of copolymers／latexes produced from microemulsion copolymerization through interracial initiation． 1．Copolymerizations of styrene(st)and N·isopropylacrylamide(NIPAM)were carried out through interfacial-initiated microemulsion polymerization at frozen state． Fourier transform infrared spectroscopy(FTIR)；nuclear magnetic resonance spectroscopy(1H NMR)and gel permeation chromatography(GPC)confirmed the occurrence of copolymerization between those two monomers．Differential scanning calorimetry(DSC)analysis showed the existence of two glass transition temperatures of the resulted copolymers．The micellization of the copolymers were investigated by dynamic light scattering(DLS)and the temperature-responsive behavior of the resulted micelles was observed．DSC and DLS results revealed the block feature of obtained copolymers．Thus amphiphilic poly(styrene-b·N-iospropylacrylamide) (PSt—b—PNIPAM)was prepared through one·step interfacial—initiated micreoemulsion polymerization． 2．Interfacial-initiated copolymerizations of acrylic acid(AA)and styrene(St)by the redox initiation couple of cumene hydroperoxide(CHPO)and ascorbic acid(ASA) were carried out in inversed microemulsion using Tween 80 and Span 80 as surfactants mixture．FTIR analysis confirmed the copolymerization of two monomers； Core—shell structure can be observed clearly from TEM photos；DLS results revealed that the particle size increased with the increasing amount of initiators． II 3．Interfacial—initiated 3．Interfacial—initiated microemulsion copolymerizat