金属离子和醋酸根离子对煤粉燃烧过程中氮氧化物生成的影响-工程热物理专业论文.docxVIP

摘 摘 要 污染物NOx对环境、气候和人类的健康影响日益严重，成为一个迫切需要 解决的问题。火电厂燃煤产生的NOx是排放的主要来源。然而NOx的生成机理 尤其是燃料型NOx生成机理及其复杂，人们至今还不完全清楚。 本文在固定床反应器中进行试验研究，燃烧温度由KSY智能型控制仪控制， 烟气采样后经过ROSEMOUNT烟气分析仪进行在线监测。我们首先对格理坪无 烟煤和神木，吉化烟煤的燃料氮析出特性进行了深入的研究，全面考察了温度和 通氧量a对NO和N20析出浓度和转化率的影响，为低Nox燃烧系统的开发和 设计提供理论基础和数据支持。 其次我们向煤粉中添加CaO、Na2C03和醋酸镁，配制成含有三种不同添加 剂和三种不同配比的样品，在相应工况下和原煤燃烧进行对比，得到NO和N20 析出特性和转化率的变化规律；并对不同工况进行比较，得到每种添加剂具有最 佳催化还原效果的工况。 文章最后对含有三种添加剂的试样进行全面的比较，得到不同工况下具有最 佳催化还原效果的添加剂，从而为NO。催化还原的研究提供理论依据；并对进 一步工作提出了自己的见解。 关键词：高温定碳炉燃烧NO。添加剂催化还原 ABSTRACTNOx ABSTRACT NOx controlling is an emergent problem at present because of its influence on environment，climate and people’S health．Power plants’coal combustion is the main source of NOx emission．But SO far as the problem appeared，people still understand liRle knowleage about the mechanism ofthe Fuel·NOx production and complexity． Combustion experiment was taken part with a fixed—bed reactor．Temperature was controlled by KSY intelligent equipment and flue gas was monitored on line by ROSEMOUNT analyzing equipment．We studied Fuel-N release characteristics of Geliping anthracite coal and Shenmu，jihua bituminous coal at first．we found Fuel-NOx increased as temperature and excess air coefficient．All of these Can offer some theoretic bases and data support to low NOx combustion system’S development and design． Secondly CaO，Na2C03 and Mg(CH3COO)2 was added into pulverized coal in order to make up three proportion samples with three additives．NOx of samples was compared to those of raw coals SO as to found the NO and N20 release characteristics and conversion ratio in the same condition．Simultaneously many kinds of conditions were compared in order to found the best experiment condition of each additives． Finally those samples with three additives were compared which we could found the best additive with catalysis in different conditions．We could support theoretic bases for NOx-catalyzing with all of these and advised some ideas for improving experiment． Key words：combustion；NOx