金属基碳纳米管（碳纳米纤维）电接触复合电镀层的制备及表征-微电子学与固体电子学专业论文.docxVIP

CARBON NANOTUBE(NANOFIBER) ELECTRIC CONTACT COMPOSITE FILMS’ PREPARATION AND PROPERTIES ABSTRACT Carbon nanotubes and carbon nanofibers were found fifteen years ago. They have high tensile strength, high chemic stability, high thermal and electrical conductivity, in addition to excellent field emission property. Therefore their practical application attracted many researches. For example, as reinforcements, they can improve various properties of composite material. In this research, these composite materials were used as electric contact material. To make carbon nantubes and carbon nanofibers enhance the metal matrix, there are still two problems which the researchers must solve: (1) carbon nantubes and carbon nanofibers must be dispersed uniformly in the metal matrix; (2) carbon nantubes and carbon nanofibers must be combined very well in the metal matrix. In this research, to prepare the carbon nantube and carbon nanofiber Cu/Ag composite films with the reinforcements dispersed uniformly and combined well in the matrix, a series optimized experiments had been done, including plating bath, current density and agitation method. Moreover, the ultrasonic agitation electric plating achieved a perfect effect, and the principle of how ultrasonic agitation works was discussed. After having prepared carbon nanotube and carbon nanofiber Cu composite films, the hardness and electric conductivity of them were also tested. The hardness of carbon nanotube Cu composite film did not enhance a lot compare with pure Cu film, while the hardness of carbon nanofiber Cu composite film enhanced obviously to 207HV. The resistivity of carbon nanotube and carbon nanofiber Cu composite films were 2.656×10-6?·cm and 1.815×10-6?·cm, both of them had a higher electrical conductivity than traditional composite electric contact material. These composite films were produce to be different kinds of electric contactors. The arc erosion test indicated that they have excellent arc erosion property, a