金属纳米孔阵列的表面增强拉曼光谱研究-光学专业论文.docxVIP

万方数据 万方数据 摘要 摘 要 由于拉曼光谱具有：对样品无接触，无损伤；样品无需制备；快速分析，鉴 别各类材料的特性与结构；能合适黑色和含水样品；可在低温及高温条件下测量； 光谱成像速度快、简单，以及分辨率高等一系列的优点，使得其被广泛地应用于 材料物理、生物医学、表面科学等研究领域中。但是拉曼光谱信号强度非常弱这 一缺点，极大地限制了拉曼光谱的广泛应用。而表面增强拉曼散射的出现，可以 很好地解决这一问题。金属纳米颗粒（孔）阵列可以通过调节颗粒（孔）的尺寸、 形貌和结构，使其在某一个波长发生表面等离子体共振，从而达到电场极大的增 强，进而实现表面增强拉曼光谱的目的。 本论文的工作是从理论上定量研究金膜的菱形纳米孔阵列孔的大小对电场的 影响，以此来探讨菱形孔阵列孔尺寸对拉曼增强的效果。再从实验上验证菱形孔 对拉曼增强的效果。主要内容包括以下几方面： 1. 借助于 FDTD Solutions 软件对金膜上的菱形孔阵列的电场分布进行分析, 并以此为依据来优化菱形孔阵列的尺寸。计算发现，LSP 对菱形孔阵列的尺寸非 常敏感（约 2nm），这对目前的纳米加工技术水平来说，几乎是没有办法达到的。 所以在对菱形孔尺寸的优化时，可以只考虑 SPR。 2. 使用计算出来的菱形纳米孔阵列的数据，使用 FIB 进行加工。然后对加工 的结果进行拉曼光谱测试。从测试的结果来看，实验的结果与理论基本上趋于一 致。 关键词：金属纳米孔阵列，表面增强拉曼散射，表面等离子体共振，局域表面等 离子体共振，时域有限差分法 I ABSTRACT ABSTRACT Because of a set of the advantages of Ranam Spectrum, such as: no touch and no damage the samples; no need to prepare the samples; quick analyses and the defining the characters and structures of different of materials; being suited to the black sample in water; and measuring under the conditions of high t or low temperature, Raman spectrum is widely used to Materials Physics, Biomedicine, and Surface Science, etc. However, the intensity of the spectrum is so weak that the study of the usage is very limited. And then surface enhanced Raman scattering (SERS) was discovered, a way to solve the problem was found accordingly. The SERS substrates, metallic nanoparticle or nanohole arrays, can excite the surface Plasmon resonant by tailoring the size, the shape of the particles or holes, changing the structures of the arrays, to achieve the aim that enhancing the electronic field and SERS. The main work of this paper, is studying how the size of the nanoholes of the array impinge on the enhancement of the electric field firstly; secondly is verifying the enhancement. That can be described as follows: Study the distribution of the electric field on the Au film with rhombus hole array, then optimize the size of the array. In this process, we discovered that, Localize Surface Plasmon Resonant (LSPR ) is very inte