金属纳米粒子石墨烯复合催化剂的组装及其在电催化方面的应用-物理化学专业论文.docxVIP

中文摘要金属纳米粒子/ 中文摘要 金属纳米粒子/石墨烯复合催化剂的组装及其在电催化方面的应用 II II (4) 采用简单的方法合成了聚多巴胺还原并修饰的氧化石墨烯复合材料 (PDA-RGO)，并以此为载体负载不同 Pt/Au 比例的 PtAu 纳米粒子。所制备的 PtAu/PDA-RGO 复合材料采用 TEM、HRTEM、Raman、EDX、XRD、XPS 以及 电化学测试进行了分析。结果发现，聚多巴胺(PDA)在提高催化剂的分散性和稳 定性方面起着非常重要的作用。相比于单金属 Pt/PDA-RGO 催化剂，双金属 PtAu/PDA-RGO 催化剂对甲醇的氧化具有较高的电催化活性，Pt/Au 比例为 3:1 时，催化效果最好。此外，PtAu(3:1)/PDA-RGO 催化剂的对甲醇的催化性能还高 于 PtAu(3:1)/RGO 和 PtAu(3:1)/C 催化剂，表明 PDA-RGO 有希望在燃料电池载 体方面得到应用。 (5) 以 1,6-己二胺功能化的石墨烯作为载体(HD-RGO)，负载 Pd 纳米粒子， 制备出了一种新型的复合催化剂 Pd/HD-RGO。所制备的复合催化剂通过 FTIR、 XPS、SEM、TEM、XRD 以及电化学测试进行了详细的表征。电化学实验结果 表明，相比于 Pd/RGO 和商业的 Pd/C 催化剂，Pd/HD-RGO 催化剂在碱性条件下 乙醇氧化表现出高的催化性能、好的抗毒化性能和稳定性能。 关键词：燃料电池，石墨烯，金属纳米粒子，甲醇，乙醇，电催化氧化 作 者：任芳芳 指导老师：杨 平 教授 杜玉扣 教授 金属纳米粒子/ 金属纳米粒子/石墨烯复合催化剂的组装及其在电催化方面的应用 英文摘要 III III Fabrication of Metal Nanoparticles/Graphene Composite Catalysts and Their Applications in Electrocatalytic Aspects Abstract Fuel cell is a kind of energy converse device, which can directly turn the chemical energy of the fuel into electrical energy. Fuel cell has very important significance in solving the two major problems of environmental pollution and energy crisis facing the world today, which has attracted considerable attention by reserachers all over the world. So far, Pt has been widely used as the anode catalyst for fuel cell. However, the nature reserves, high price and poor anti-poisonous of Pt severly hamper the commercialization of fuel cell. Therefore, decreasing the amount of Pt and increasing the catalytic activity of the catalyst have always been the research hotspots of fuel cell. Studies have shown that catalyst support plays a significant role in minimize the usage and maximize the catalytic activity of catalyst. Graphene has been considered as an ideal catalyst support for fuel cell owing to its large specific surface area, good electrical conductivity and excellent thermal/chemical stability. In this dissertation, chemical and electrochemical methods have been employed to prepare a series of metal/graphene composite catalyst