金属纳米微粒的表面增强拉曼散射分析-分析化学专业论文.docxVIP

东北大学硕士学位论文 东北大学硕士学位论文 摘要 金属纳米微粒的表面增强拉曼散射研究 摘 要 本论文采用纳米自组装技术和扫描探针显微技术，进行了金属纳米微粒的表 面增强拉曼散射(SERS)的研究。 本实验成功地制备了一种新型的SERS活性基底，即将金属纳米微粒组装于十 六烷基三甲基溴化胺(CTAB)修饰的云母表面上所制备SERS活性基底。以Ag 纳米微粒为表面增强物质，以罗丹明6G(Rh6G)为探测分子，与其它几种常用的 SERS活性基底进行了比较研究。结果表明，这种新型的SERS活性基底是一种有 效的、具有超高灵敏度的活性基底。并利用这种SERS活性基底，研究了PtCOI。-Ag。hcll 和Ptc。。．Aushell两种复合纳米微粒的表面增强能力和测定的稳定性。原子力显微镜 (AFM)研究表明，Ptc。FAg。hell和Pt。。一Allshell两种复合纳米微粒多呈球状，平均 粒径分别为14．3nm和5．1nm，标准偏差分别为1．8nm和O．4nm，粒径分布均优于 采用类似方法制备的单金属Ag和Au纳米微粒；将Ptc。诅＆h。ff和P匕。．A地捌l两种 复合纳米微粒自组装在由CTAB修饰的云母表面，进行这两种复合纳米微粒的表 面增强能力的研究。结果表明，这两种复合纳米微粒具有较强的表匠增强能力， 对于Rh6G，可检测到的最低浓度分别为4．4x 10‘2 u g／L和4．4X 10。2mg／L；对于一 定浓度的Rh6G，在1650em。1处峰强度的相对标准偏差分别为18．56％和12．71％， 测定结果的重现性较好。 关键词； 纳米微粒表面增强拉曼散射 II 查!!苎兰堡主堂堡垒查 查!!苎兰堡主堂堡垒查 垒堕塑生 Studies on Metallic Nanoparticles of Surface．Enhancement Raman S cattering Abstract In this work，we studied on Surface—Enhancement Raman Scattering of several kinds ofmetallic nanoparticles． By self-assembly of metallic nanoparticles on mica coated with Cetyltrimethyl_ amlnonil,lm Bromide(CTAB)，a new kind of SERS active snhstmtes was formed．As Ag nanoparticles enhanced substance，the result showed this kind of substrates Was effective and ultra。sensitive SERS active substrate．Using this kind of substratcs，the enhanced abilities of Ptcofe—A昏heII and Ptcore—Aus hell nanoparticles were studied．Studies on AFM showed that most of Ptcofe-AgsheU and I’tc0代·A％1eII nanoparticles were spherical and well proportioned for their size was 14．3nm and 5．1nm,respectively and their standard deviation was 1．Snm and O．4nm，respectively．And the scopes of the nanoparticles were also smaller than single Ag and single Au nanoparticles．Studies on SERS showed the enhanced abilities of Ptcom·A昏hdl and Ptc叭-Aushell nanoparticles were strong．for也e concentration of the lowest detection of Rh6G was 4．4×10。u g／L and 4．4 X 10之mg／L．respectively,and the repetition Was also good for the RSD of the peak intensity on 1650em～Was 18．56％and 12．71％，respectively． Key words：nanoparticles，surface enha