金属氧化物复合材料的微波吸收特性-物理化学专业论文.docxVIP

兰州人学硕士学能论文酒精为过程控制剂时，随球磨时间增加，球形羰基铁粉颗粒逐渐躺平化为片 兰州人学硕士学能论文 酒精为过程控制剂时，随球磨时间增加，球形羰基铁粉颗粒逐渐躺平化为片 形，且球磨时间越长，片形颗粒的厚度越小。这样的形貌变化可能是随球磨时间 增加样品的磁谱在大约500 MHz显示～个越来越明显的畴壁共振峰的原因。 (3)使厢Stober方法在片形攘基铁粉颗粒的表面包覆了一层很薄的非晶 Si02，得至g片形Fe／Si02核壳结构颗粒。包覆Si02后，片形羰基铁粉颡粒的介电 常数大幅下降，已经比较接近磁导率，从磊达到较为理想的阻抗匹配，微波吸收 性能大幅提高。通过改变包覆时闻，得到Si侥层厚度分别为20 nnl、60 nm和 70 nm的Fe／Si02核竟结构颗粒。Si02层厚度对样品的高频特性调控有限，三个 不同Si02层厚度的样品的微波吸收性能基本相同。 (4)把使用传统共沉淀方法制备的Nio．sZno．5Fe204粉末和羰基铁粉混合球磨 后得到F洲沁Zno。5Fe204复合材料。对于Ni0．5Zno+5Fe204和羰基铁粉质量比为1：9 的样品，隧着球瘗时闻增加，样晶颗粒逐渐由片形变成不规则形状，导致其介电 常数和磁导率逐渐下降。由于随球蘑时间增加样品介电常数下降，使徭阻抗匹配 变好，样品的微波吸收性能提升。对予不圈Ni。，5Zno．5Fe204和羰基铁粉质蘩院的 样品，随着样品中Nio．5Zno。5Fe204含量的增加，样品的介电常数和磁导率逐渐下 降，阻抗匹配逐渐变好，样品的微波吸收性能得到提升。 关键词：金属，氧化物，复合材料，磁性材料，微波吸收 Il 兰州人学硕_上．学位论文Abstract 兰州人学硕_上．学位论文 Abstract With the rapid development of wireless communications and high-frequency circuit devices in the gigahertz range，electromagnetic interference(EMI)problems have attracted increasing attention recently．Many kinds of microwave absorption materials(MAM)have been studied with the objective of solving the EMI problems． Among all MAMs，metallic magnetic materials are especially focused on due to high saturation magnetization，high permeability,high Curie temperature and low coercivity．However,the high electrical conductivity and high dielectric constant of metallic magnetic material limit the application．The composite materials cantaining metallic magnetic material and certain insulation material may be a way to solve these problems． In the work，three series of metal—oxide composite materials were prepared using ball milling method assisted by some chemical methods，and the effect of preparation conditions on the morphology,structure，static magnetic properties and microwave absorption characteristics was explored．The main results are as follows： (1)FeCo／A1203 composite material was prepared using mechanochemical method．The reaction is quick，and the XRD pattem shows there are only the diffraction peaks of FeCo and A1203．In one particle，the FeCo and A120