有机酸对污染底泥中Zn和Pb浸出的影响.PDF

中国环境科学 2010,30(9) ：1235~1240 China Environmental Science 有机酸对污染底泥中 Zn 和 Pb 浸出的影响 * 李 鹏, 曾光明 ,徐卫华,张 长,蒋 敏 (湖南大学环境科学与工程学院,环境生物与控制教育部重点实验室, 湖南 长沙 410082) 摘要：采用 2 种污染底泥, 比较研究 3 种低分子有机酸及 pH 值对底泥中重金属 Zn 和 Pb 浸出的影响.结果表明,3 种低分子有机酸对供试底 泥中 Zn 和 Pb 都具有浸出作用,有机酸对 Zn 的浸出能力大小为:柠檬酸苹果酸酒石酸;对 Pb 浸出能力大小为:柠檬酸酒石酸苹果酸.Zn、 Pb 的浸出浓度随有机酸浓度的升高和 pH 值的降低而增加,有机酸对重金属的浸出能力大于无机盐.在有机酸条件下,底泥中重金属的浸出 能力为:ZnPb. 关键词：低分子有机酸；底泥；重金属；pH 值；浸出浓度 中图分类号：X132 文献标识码：A 文章编号：1000-6923(2010)09-1235-06 * Effects of organic acids on zinc and lead leaching from contaminated sediments. LI Peng, ZENG Guang-ming , XU Wei-hua, ZHANG Chang, JIANG Min (Key Laboratory of Environmental Biology and Pollution Control, College of Environmental Science and Engineering, Hunan University, Changsha 410082, China). China Environmental Science, 2010,30(9) ：1235~1240 Abstract ：The leaching characteristics of zinc and lead in two contaminated sediments were studied, and the effect of low molecular weight organic acids (LMWOAs) and pH value on the leaching of zinc and lead from two contaminated sediments were examined. The results showed that zinc and lead in the sediments were partly dissolved by three LMWOA solutions under different concentrations in batch experiment. The leaching of heavy metals from two sediments followed the descending order: citric acid malic acid tartrate acid (for zinc); citric acid tartrate acid malic acid (for lead). The leaching concentrations of heavy metals in solution were enhanced with the increasing of LMWOA concentration and the decreasing of pH value. In addition, all LMWOAs leached more heavy metals than inorganic salt did. The leaching capability under the con