取代二苯胺重氮盐重氮树脂合成及光热分解性质-影像科学与光化学.PDF

15 1 Vol. 15, No. 1 1997 2 PHOT OGRAPHIC SCIENCE AND PHOT OCHEM IST RY Feb. , 1997 研究简报 * * * 鲁宁莉 曹维孝 ( , 100 71) 取代二苯胺重氮盐, 重氮树脂, 热分解 [ 1] PS , [2 5] . , PS , , . , , , 3 [6, 7] 4, . , 24( ) , , 4, 4( ) , . 1 1. 1 [ ] 24( ) . 2, 44 , : 5 g( 0. 025 mol) 2, 4, 2. 7 g( 0. 025 mol) , 4 g , 0. 19 g , 30 mL , 1 h, , . , , , , 4. 5 g( 60%) . : 3. 5 g( 0. 013 mol) 2, 44, 15 mL , , 1. 04 g( 0. 015 mol) ( 1 mL ) , 0. 5 h, . 1 mL 40%, 2, 44 1996 5 10 , 1996 7 1 . * * * 75 76 15 , 1. 92 g( 40% ) . 1. 2 [3] , : 1. 5 g(4. 7 mmol) 2 4, 0. 17 g( 5. 6 mmol) ( ) 4 mL , 3 h 4 mL , , , , 0. 5 g( 52%) . [9] 4, 4( ) , : 1. 4 g (4. 4 mmol) 242. 5 mL 5% , 40 1. 1 g(4. 4 mmol) 4, 4( ) , 6 h 40 mL , , , , 1. 15 g( 4 % ) . 4, 4( ) [ 10] 4, 4( ) . ( ) . 1. 3 , , . , . 250 . DSC , DT30 . 1 The elem ental analysis data of substituted diphenylamines and their diazonium salts 1 : 77 2 1 . , . 4 - 1 370 nm , 10 Lmol cm- 1, . , , U VVis , . , , . 1 2 424 . , . 1 4 2 24