镀液pH值和钼酸根浓度对化学镀Ni-Mo—P沉积速度及镀层结构的影响.PDFVIP

44 镀液pH 值和钼酸根浓度对化学镀Ni–Mo–P 沉积速度及镀层结构的影响 卢忠铭 等 镀液pH 值和钼酸根浓度对 化学镀Ni–Mo–P 沉积速度及镀层结构的影响 卢忠铭 高 岩 郑志军 华南理工大学 机械工程学院 广州510640 摘 要: 确定了化学镀获得不同结构Ni–Mo–P 镀层的最佳工艺参数及镀液配方 探讨了络合剂 pH 值 钼酸根浓度 以及添加剂等参数对化学镀Ni–Mo–P 合金镀层成分及结构的影响 结果表明 以柠檬酸钠作为主络合剂 醋酸钠作为 辅助络合剂的络合剂体系对Ni Mo 实现共沉积有着较好的作用 Ni–Mo–P 合金镀层中Mo 和P 含量有一定的制约关 系 随着镀层中Mo 含量的提高 镀层结构由非晶态向晶态转变 镀液pH 值在一定范围内(pH 值6.5 10)时 pH 值 的升高可提高沉积速度 镀液的钼酸根浓度和pH 值对沉积速度的影响呈波浪形 存在一个极大值 随着沉积速度的 提高 镀层的耐蚀性能也会有所改善 关键词 化学镀Ni–Mo–P 合金镀层 镀层结构 工艺参数 中图分类号 TG115 TQ153 文献标识码 A 文章编号 1007–9289(2005)02–0044–06 The Effect of pH Value and MoO42- Concentration on the Plating Rate and Structure of Electroless Ni–Mo–P alloys LU Zhong-ming, GAO Yan, ZHENG Zhi-jun (College of Mechanical Engineering, South China University of Technology, Guangzhou 510640 China) Abstract: The optimized plating bath formula and plating parameters for the electroless Ni–Mo–P alloy deposits with different structures were determined in this paper. The effect of plating parameters, such as complex agents, pH value, MoO42- concentration and additives, on the composition and structure of the Ni– Mo–P alloy deposits was investigated. The experimental results showed that among the complex agents used, only one made from sodium citrate tribasic dihydrate (C H Na O · 2H O) and sodium acetate trihydrate (CH COONa· 3H O) was found to be helpful to the co-deposition of Ni and 6 5 3 7 2 3 2 Mo to get good Ni-Mo-P alloy deposits. In the Ni–Mo–P alloy deposits t