微波辐射多相催化合成乙酸丁酯.PDFVIP

20 10 1 27 1 Jan. 20 10 CHEM ICAL INDU STRY AND ENG INEER ING V o l. 27 N o. 1 : 1004 - 9533( 20 10 01- 0017 - 04 1 1 2 3 柳艳修 , 李丽荣 , 张铁晶, 张文超 ( 1, 163318; 2, 163714; 3, 163714 : 在微波辐射条件下, 研究了H ZSM 5 为催化剂的多相催化酯化法合成乙酸丁酯的反应探讨 了催化剂用量微波辐射 率微波辐射时间和吸水剂用量对反应的影响在适宜的反应条件下: V( 乙酸 / V(正丁醇 = 16, H ZSM 5分子筛为 0094 g /mL ( 以乙酸计 , 微波辐射 率 640 W, 微波 辐射时间 30 m in, 吸水剂 (氯化钙 0375 g /mL ( 以乙酸计 , 酯收率达 987% : 乙酸丁酯; HZSM 5; 微波 : O623624+ . 1 : A HeterogeneousEsterification for the Synthesis of ButylAcetate under the Condition ofM icrowave Irradiation 1 1 2 3 L IU Y anx iu , L I L irong , ZHANG T iejing , ZHANG W enchao ( 1. C hem istry and Chem ical Eng ineering Col lege, D aq ing P etroleum In stitute, D aqing 163318, Ch ina; 2. D aq ing Ch em ical Plan t 1, D aq ing P etrochem ical C om pany, D aqing 1637 14, Ch ina; 3. D aq ing P etrochem ical E ngineering Co. Ltd. , D aq ing 1637 14, Ch ina Abstract: T he synthesis of buty l acetate from acet ic acid and nbutano l over H ZSM 5 catalyst under the condition of m icrow ave irradiat ion has been stud ied. T he effects of am ount of catalyst, m icrow ave pow er, radiation tmi e and am oun t of w ater absorbent w ere investigated. U nder the su itable conditions, i. e. , the vo lum e ra tio of acetic acid to nbutanol o f 16, the am oun t of H ZSM 5 of 0094 g /mL ( calcu lated based on