烟煤燃烧过程中多环芳烃生成研究.PDFVIP

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第22 卷 第12 期 中 国 电 机 工 程 学 报 Vol.22 No.12 Dec.2002 2002 年12 月 Proceedings of the CSEE ©2002 Chin.Soc.for Elec.Eng. 文章编号: ( ) 0258-8013 2002 12-0127-06 烟煤燃烧过程中多环芳烃生成研究 李晓东,祁明峰,尤孝方,严建华,池 涌,倪明江,岑可法 (浙江大学热能工程研究所,能源洁净利用与环境工程教育部重点实验室,浙江杭州 310027) STUDY ON THE FORMATION OF POLYCYCLIC AROMATIC HYDROCARBON (PAH)MECHANISMS IN BITUMINOUS COAL COMBUSTION PROCESS LI Xiao-dong, QI Ming-feng, YOU Xiao-fang, YAN Jian-hua, CHI Yong, NI Ming-jiang, CEN Ke-fa (Clean Energy and Environmental Engineering Key Laboratory of Ministry Education, Zhejiang University, Hangzhou 310027, China) ABSTRACT: Some organic pollutants are emitted in coal NOX ,CO,还产生少量有机污染物如多环芳烃等, combustion process. Organic pollutants such as polycyclic 虽然产生的量比常规污染物相对较少,但是由于它 aromatic hydrocarbons (PAHs), which are carcinogenic and 们有强致癌、致畸、致突变作用,所以随着人们生 mutagenic compounds to human health, are concerned widely. [1] 活水平的提高和认识的深化,也日益得到关注 。 An experiment for coal combustion in a small pipe oven is reported with its results. The emission performance of 17 PAHs, 多环芳烃是石油、煤炭等化石燃料以及木材、 which contains the 16 PAHs specified by the US Environmental 纸张、作物秸秆、烟草等含碳氢化合物的物质,经 Protection Agency, is studied under different combustion 不完全燃烧或者在还原性气氛中经热分解生成 conditions. The factors affected the PAHs fate and destruction, [2] 的 。有数据表明锅炉燃烧产生的苯并[a]芘约占多 and mechanisms for PAHs formation in combustion process are [3] 环芳烃总排放量的 51.6% 。煤的完全热解能使大 also discussed. 的有机分子变成较小的碳氢化合物,在完全燃烧时 KEY WORDS : pol

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