以蒸气注入法去除土壤中柴油之研究.DOC

以蒸氣注入法去除土壤中柴油之研究 Using Steam Injection Technology on Remediation of TPH-D Contaminated Soils 研究生：郭惠菁 Kuo, Hui-Ching 指導教授：薩支高 Sah, Jy-Gau 【摘要】 加油站及大型儲槽為油品污染最常發生之地點，一旦油品進入環境中，可能透過食物鏈進入人體或對環境生態造成破壞。液態或高溫蒸氣態水皆具有性質穩定、操作安全、價格便宜及無二次污染土壤之優點，本研究主要利用熱蒸氣注入遭柴油污染土壤中，觀察以不同注入方式、土壤質地、污染物濃度及土壤有機質等參數對污染物濃度移動變化之情形，並比較不同溫度水洗受柴油污染之土壤。 研究結果顯示，蒸氣溫度對於柴油之移動(削減)有重要之影響，距離蒸氣注入點D點(距蒸氣出口0 公分處)土壤中柴油含量減少最多，其次依序為C點(距蒸氣出口8 公分處)B點(距蒸氣出口16 公分處)≧A點(距蒸氣出口24 公分 關鍵字：蒸氣注入法、柴油污染土、熱水水洗 【Abstract】 Soil and ground water petroleum contamination are often happened under gas station or storage tank. Once those pollutants flow into the environment, they may damage the ecosystem or people health. Liquid and steam water are stable and non-expensive material that can be safely used to remove pollutants from soil. The objective of this study is to investigate the trend of TPH-D by injecting steam into TPH-D contaminated soils. We focus on the difference types of injection, soil textures, TPH-D concentrations and soil organic matters which can influence the TPH-D movement in soil. The results indicated that the movement of TPH-D was influenced by steam temperature. The greatest decrease was at D point (0 cm from the steam injection outlet). Followings were C point (8 cm from the steam injection outlet) B point (16 cm from the steam injection outlet)≧A point (24 cm from the steam injection outlet). The steam injection efficiency in lower soil sand ratio (1:1) was better than in higher one (3:1) because of the porosity, soil surface area and soil organic matter content. Although the soil contain 5 % diesel had sufficient remove efficiency after 8 hours of steam injection, it still had 2 % TPH-D remaining in soil. Longer steam injection time was HYPERLINK /search?ei=UTF-8p=%E5%BB%BA%E8%AD%B0 suggested to reduce the remaining TPH-D. After most TPH-D was removed to the top soil in 1wt% contaminated soil, we suggest 8 cm top soil should be excavated. The hot soil washing experiment showed that higher temperatu