基于酰肼和蒽醌的多响应小分子有机凝胶体系的研究-物理化学专业论文.docxVIP

兰州大学博士论文刘佳伟(2)阴离子响应尽管这种凝胶因子中生色团蒽醌和氢键单元通过。键相连，但是氯仿凝胶能够对特定的阴离子做出双重响应：凝胶到溶液的转化和颜色的变化．由于这种响应的根本原因是脱质子化作用，所以加入甲醇后能够使颜色变化消失并且实现由溶液到凝胶的转化．(3)超声响应虽然凝胶因子lc．1e在DMSO以及甲醇等强极性有机溶剂中不能形成有机凝胶，但是在他们的热溶液冷却时用超声波进行刺激则可以形成稳定的凝胶。并且超声波刺激可以极大改变凝胶的形貌。(4)有机凝胶的应用凝胶因子lb．1e可以在水和有机溶剂的混合物中选择性的使有机溶剂凝胶化。另外，通过有机凝胶制备的干凝胶可以从水溶液中吸附甲基紫等染料分子。这种凝胶因子的染料吸附能力可以用于水的纯化。关键词：酰肼；低分子量有机凝胶因子；结构；有机凝胶：刺激响应；应用II兰州大学博t论文刘佳伟AbstractOrganogelsarecomposedofaself-assembledsuprastructureoflowmolecular-massorganicgelators(LMOGs)throughweakintermolecularinteractions(suchashydrogenbondsetc)andalargevolumeofliquidimmobilizedtherein．Becauseoftheiruniquestructuresandwideapplicationsintemplatedsynthesisofnano—scaleinorganicmaterials，oilrecovery,organicsoftmaterials，opticalsensors，slowdrug—deliverysystemsandSOon，studiesonorganogelshavebeenthesubjectofincreasingattentioninmaterialsscienceandsupramolecularchemistryinrecentyears．Recently．thedevelopmentof‘‘smart”or‘‘responsive’’gelshasbeenespeciallyappealingforpotentialapplications．Thus，someexamplesonthesol-geltransitiontunedbytheenvironmentalstimuli，suchaslight，ionicstrength，electricormagneticfields，mechanicalstress，pHchanges，molecularrecognitionandultrasoundhavebeenreported．Thereversiblenatureofsupramoleculargelsseemsidealfortheuseofstimulus—controlledcatalyticsystemsbyenvironmentalstimuli．Thispapercontainsthefollowingsections：1Thesynthesisofsmallmoleculeorganicgelsfactorbasedonhydrazine，anthraquinoneandstudyofitsorganicgelsystemThenovellow-molecular-weightorganogelators(LMOGs)lb-lecomposedofallanthraquinoneunit，ahydrazidegroup，andlongalkylchainsweresynthesized．Studiesontheirstructure-propertyrelationshipaleintensified．Theycouldformstablegelsatconcentrationsauslowas0．1wt％intestedsolvents．Chloroalkanesandaromaticsolventstendtoresultin打ansparentgels，whilealcoholandothersolventsyieldopaquegels．Interestingly，wefurtherfoundthattheachiralgelatorcouldformsupramoleeularstructureswithwell—definedhelicalribbons．TheFT—IRPXRD，Uv-visand1HNMRspectralstudiesrevealedthathydrogenbondingand冗．兀interact