双阴极MFC启动过程中的电化学特性-环境工程学报.PDF

第 11卷　 第 12 期 环 境 工 程 学 报 Vol.11,No.12 2 0 17 年 12 月 Chinese Journal of Environmental Engineering Dec . 2 0 1 7 双阴极MFC启动过程中的电化学特性 1,∗ 1 1,2 1 张建民 ,魏佳齐 ,崔心水 ,薛瑶 1.西安工程大学环境与化学工程学院,西安 710048 2.长安大学环境科学与工程学院,西安 710064 摘　 要　 构建以污水处理厂二沉池污泥接种的双阴极微生物燃料电池(MFC),用循环伏安法(CV)、交流阻抗法(EIS)表 征了MFC启动阶段的电化学特性。 结果表明:经过 3 个周期的运行,输出电压稳定,反应器启动成功,启动阶段厌氧-好 氧和厌氧-缺氧部分输出电压的最大值分别为 175 和336 mV。 缺氧阴极,厌氧阳极电极生物膜 CV 检测中出现氧化还原 峰,随着启动时间的增加,其峰值电流逐渐增大;而好氧阴极电极生物膜的 CV 检测结果中未出现明显的氧化还原峰。 悬浮污泥的CV 检测结果中出现了成对的氧化还原峰,表明生物代谢过程中有电子中介体产生。 EIS 结果说明电极的欧 姆内阻和扩散内阻基本保持不变,极化内阻在不断减小,很好地反映了产电微生物在电极上富集的过程。 启动成功后缺 氧、厌氧和好氧电极的极化内阻值分别为2.86、2.33 和57.64 Ω,好氧阴极极化内阻值较大,表明其电极生物膜催化能力 较弱。 关键词　 双阴极 MFC;启动;电化学;循环伏安法;交流阻抗法 中图分类号　 X703　　 文献标识码　 A　　 文章编号　 1673-9108(2017)12-6252-07　　 DOI　 10.12030/ j.cjee.201705059 Electrochemical characterization of dual cathode MFC during start-up phase 1,∗ 1 1,2 1 ZHANG Jianmin ,WEI Jiaqi ,CUI Xinshui ,XUE Yao 1.School of Environment and Chemistry Engineering,Xi′an Polytechnic University,Xi′an 710048,China 2.College of Envionmental Science and Engineering,Chang′an University,Xi′an 710064,China Abstract　 In this study,the construction of the experiment was based on the double cathode microbial fuel cell (MFC),which was inoculated with the second sedimentation tank of sewage treatment plant.As for the start-up stage,the electrochemical characteristics of MFC were characterized by cyclic voltammetry (CV) and electro- chemical impedance spectroscopy (EIS) methods. The results indicated that the output voltage is stable after three cycles of operation. Thus,the reactor is started successfully. And the maximum values are 175 and 336 mV,corresponding to anaerobic-aerobic and anaerobic-hypoxia for output voltages in the start-up phase. As for the CV method,the redox peaks can be clearly observed in t