电荷转移反应的分析:量子与经典溶剂化,绝热与非绝热与马尔可夫与非马尔可夫特性.pdfVIP

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电荷转移反应的分析:量子与经典溶剂化,绝热与非绝热与马尔可夫与非马尔可夫特性.pdf

Abstract Electron the reaction but a transfer(ET)i8simplest systemplay8piv- ot甜rolein chemiealand ET many consti. biologicalprocesses.processes tuteaclass of whose onsolvent systems environmenthas dependence been studied since eXtensively contribution.This Marcus’pioneering thesisrevis— it8the electrontransferrate interestsinthedi8tinct theory,withparticular solV玑ion qu疵um the e行ect,andchara.cterizationof a11d rate Markovia.11/non—MarkoviaIlthebasisofasetofnon- proce8ses,on rate W】1ich perturbative resultfroma equations of generaltheoryquantum di8sipation. In introduce Chapter1,we someresearch in backgroundthe矗eldof theMarcusET rate andthe ET,especially Kramerschemical theory reaction haⅣehad a on theory.They the of greatimpaet tradition以rate development theories.The celebrated Marcus’iIlver8ionand Kr锄

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