等离子体光谱联用技术在元素形态分析中的分析与应用.pdfVIP

Study on the Element Speciation with Plasma Spectrometry Hyphenating Techniques and Its Application Postgraduate Student:Xu Qiumei Supervisor: Professor Deng Biyang Major: Analytical Chemistry Research orientation: Spectral Analysis Enrollment ： 2004 Abstract Inductively coupled plasma Spectrometry (ICP-AES/MS) is a advanced multi-elements trace analysis technology.It offers extending good advantages in terms of low detection limit, high precision, good selectivity, little matrix effect, wide linear range and simultaneous multi-elements determination, so it is widely used. But the routine determination of ICP-AES/MS couldn’t meet the research demand with scientific development. The hyphenating of ICP-AES/MS with analytical instruments else would combine strongpoints of them to a certain extent and so much as improves analytical capability for conquering their shortcomings so that it meets analytical demand to the best. Hydride Generation-Inductively Coupled Plasma Atomic Emission Spectrometry (HG-ICP-AES) enhance detection power of ICP-AES to hydride-forming elements. The detection limits of hydride-forming elements can be improved by one or two orders of magnitude over conventional nebulizer, and nearly eliminated matrix spectrum interference. Therefore, it provides a new way to solve complex matrix interference and speciation analysis . Capillary electrophoresis (CE) has many advantages: high efficiency , quick analysis speed , many analysis modes, little reagent consumption, wide application, easy automation, etc. Thus it shows extremely important app