含氟类萘二酰亚胺n-型有机半导体材料的设计合成及性能研究-仿生材料专业论文.docxVIP

东华大学硕士学位论文含氟类萘二酰亚 东华大学硕士学位论文 含氟类萘二酰亚胺 n-型有机半导体材料的设计合成及性能研究 II II 封端的扩环化合物（NDI-DTYP2），并研究了其物理化学性质，测试 了几种化合物的半导体性能，并对其结构—性能关系进行了研究。我 们发现，在苯环的三个不同化学位点引入单个氟原子时，材料表现出 不同的性能。当氟原子处在苯环的邻位和间位时，材料表现出典型的 n-型半导体传输电子的特征，当氟原子处在苯环的对位时，材料则表 现出 n-型主导的双极性材料的特征，既能传输电子，又能传输空穴。 当在对位用三氟甲基取代氢原子时，材料又重新变为典型的 n-型半导 体材料的特征。当苯环上的五个氢原子都被氟原子取代时，材料同样 显示出 n-型半导体材料的特征，但是材料的物理化学性质发生了重大 改变。研究结果表明：引入氟原子是对材料进行修饰的一种有效途径， 不同位置上引入氟会对材料的性能产生很大的影响，也为以后调节分 子性能提供了新方法。 关键词：萘二酰亚胺，氟，有机半导体，有机场效应晶体管 PAGE PAGE IV THE DESIGN，SYNTHESIS AND PROPERTY RESEARCH OF N-TYPE ORGANIC SEMICONDUCTOR BASED ON FLUORINATED NAPHTHALENE DIIMIDES ABSTRACT Recently, organic electronic have attracted considerable attention with the boom of the electronics industry. Organic Field-Effect Transistors (OFETs) are widely applied in organic electronics due to their advantages of easy preparation, flexibility and low-cost. Organic semiconductors, which act as the key components of OFETs, play an important role in carrier transportation, which can influence the performance of OFETs. Therefore, the development of OFETs should be based on the excellent organic semiconductor materials. To date, some p-type (hole transporting) organic semiconductors have shown high hole mobility, which already reached and even exceed the level of the amorphous silicon. In contrast, the number of n-type (electron transporting) organic semiconductors with high mobility is few. However, both the p-channel and n-channel transistors are required to construct the organic complementary logic circuits. Nowadays, naphthalene diimides (NDIs) derivatives as typical n-type organic semiconductors have gained wide attention due to their low-lying LUMO level, high thermal and chemical stability. One of the π-expanded naphthalene diimides (NDIs) derivatives are promising organic semiconductor materials, due to their good stability and high electron mobility. In addition, fluorinated compounds are widely used in biology, medicine, chemical industry and photoelectric and other f